Mechanisms of Furfural Reduction on Metal Electrodes: Distinguishing Pathways for Selective Hydrogenation of Bioderived Oxygenates

dc.contributor.author Li, Wenzhen
dc.contributor.author Chadderdon, Xiaotong
dc.contributor.author Chadderdon, David
dc.contributor.author Matthiesen, John
dc.contributor.author Qiu, Yang
dc.contributor.author Carraher, Jack
dc.contributor.author Tessonnier, Jean-Philippe
dc.contributor.author Tessonnier, Jean-Philippe
dc.contributor.author Li, Wenzhen
dc.contributor.department Ames Laboratory
dc.contributor.department NSF Engineering Research Center for Biorenewable Chemicals
dc.contributor.department Chemical and Biological Engineering
dc.date 2018-03-07T22:21:42.000
dc.date.accessioned 2020-06-29T23:23:07Z
dc.date.available 2020-06-29T23:23:07Z
dc.date.embargo 2018-09-13
dc.date.issued 2017-01-01
dc.description.abstract <p>Electrochemical reduction of biomass-derived platform molecules is an emerging route for the sustainable production of fuels and chemicals. However, understanding gaps between reaction conditions, underlying mechanisms, and product selectivity have limited the rational design of active, stable, and selective catalyst systems. In this work, the mechanisms of electrochemical reduction of furfural, an important biobased platform molecule and model for aldehyde reduction, are explored through a combination of voltammetry, preparative electrolysis, thiol-electrode modifications, and kinetic isotope studies. It is demonstrated that two distinct mechanisms are operable on metallic Cu electrodes in acidic electrolytes: (i) electrocatalytic hydrogenation (ECH) and (ii) direct electroreduction. The contributions of each mechanism to the observed product distribution are clarified by evaluating the requirement for direct chemical interactions with the electrode surface and the role of adsorbed hydrogen. Further analysis reveals that hydrogenation and hydrogenolysis products are generated by parallel ECH pathways. Understanding the underlying mechanisms enables the manipulation of furfural reduction by rationally tuning the electrode potential, electrolyte pH, and furfural concentration to promote selective formation of important biobased polymer precursors and fuels.</p>
dc.identifier archive/lib.dr.iastate.edu/ameslab_manuscripts/43/
dc.identifier.articleid 1052
dc.identifier.contextkey 11161590
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath ameslab_manuscripts/43
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/7376
dc.language.iso en
dc.relation.ispartofseries IS-J 9446
dc.source.bitstream archive/lib.dr.iastate.edu/ameslab_manuscripts/43/IS_J_9446_just_accepted.pdf|||Sat Jan 15 00:15:12 UTC 2022
dc.source.uri 10.1021/jacs.7b06331
dc.subject.disciplines Bioresource and Agricultural Engineering
dc.subject.disciplines Environmental Chemistry
dc.subject.disciplines Sustainability
dc.title Mechanisms of Furfural Reduction on Metal Electrodes: Distinguishing Pathways for Selective Hydrogenation of Bioderived Oxygenates
dc.type article
dc.type.genre article
dspace.entity.type Publication
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