BODIPY-Derived Photoremovable Protecting Groups Unmasked with Green Light Smith, Emily Goswami, Pratik Ayed, Aleem Winter, Arthur Beck, Christie Albright, Toshia Mahoney, Kaitlyn Unash, Ryan Smith, Emily Winter, Arthur
dc.contributor.department Chemistry 2018-02-17T06:39:38.000 2020-06-30T01:17:38Z 2020-06-30T01:17:38Z Thu Jan 01 00:00:00 UTC 2015 2015-01-01
dc.description.abstract <p>Photoremovable protecting groups derived from <em>meso</em>-substituted BODIPY dyes release acetic acid with green wavelengths >500 nm. Photorelease is demonstrated in cultured <em>S</em>2 cells. The photocaging structures were identified by our previously proposed strategy of computationally searching for carbocations with low-energy diradical states as a possible indicator of a nearby productive conical intersection. The superior optical properties of these photocages make them promising alternatives to the popular <em>o</em>-nitrobenzyl photocage systems.</p>
dc.description.comments <p>This article is from <em>Journal of the American Chemical Society</em> 137 (2015): 3783, <a href="" target="_blank">doi:10.1021/jacs.5b01297</a>. Posted with permission.</p>
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dc.identifier archive/
dc.identifier.articleid 1126
dc.identifier.contextkey 7878235
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath chem_pubs/123
dc.language.iso en
dc.source.bitstream archive/|||Fri Jan 14 19:17:47 UTC 2022
dc.source.uri 10.1021/jacs.5b01297
dc.subject.disciplines Complex Fluids
dc.subject.disciplines Materials Chemistry
dc.subject.disciplines Other Chemical Engineering
dc.subject.disciplines Other Chemistry
dc.title BODIPY-Derived Photoremovable Protecting Groups Unmasked with Green Light
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication 1593ba6f-2eb3-4290-ab73-86b7601506fa
relation.isAuthorOfPublication a2121da6-c591-494f-b9a9-595265e46ff9
relation.isOrgUnitOfPublication 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11
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