Oscillatory dynamics in a heterogeneous surface reaction: Breakdown of the mean-field approximation

dc.contributor.author Vigil, R.
dc.contributor.author Willmore, Frank
dc.contributor.department Chemical and Biological Engineering
dc.date 2018-02-13T22:00:30.000
dc.date.accessioned 2020-06-30T01:10:55Z
dc.date.available 2020-06-30T01:10:55Z
dc.date.copyright Mon Jan 01 00:00:00 UTC 1996
dc.date.embargo 2014-02-26
dc.date.issued 1996-04-01
dc.description.abstract <p>Hierarchical mean-field rate equations and lattice-gas simulations were developed to elucidate the effects of the breakdown of the mean-field approximation for a model heterogeneous chemical oscillator that represents a simple extension of the well-known monomer-dimer surface reaction model. The bifurcation structure of the reaction kinetics depends sensitively on the details of surface transport processes, and the oscillatory behavior exhibited by the site approximation rate equations is not generally robust with respect to spatial correlations.</p>
dc.description.comments <p>This article is from Physical Review E 54 (1996): 1225-1231, doi:10.1103/PhysRevE.54.1225. Posted with permission.</p>
dc.format.mimetype application-pdf
dc.identifier archive/lib.dr.iastate.edu/cbe_pubs/93/
dc.identifier.articleid 1094
dc.identifier.contextkey 5222302
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath cbe_pubs/93
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/13596
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/cbe_pubs/93/1996_VigilRD_Oscillatory_dynamics_in_a_heterogeneous_surface_reaction.pdf|||Sat Jan 15 02:30:57 UTC 2022
dc.source.uri 10.1103/PhysRevE.54.1225
dc.subject.disciplines Catalysis and Reaction Engineering
dc.subject.disciplines Chemical Engineering
dc.title Oscillatory dynamics in a heterogeneous surface reaction: Breakdown of the mean-field approximation
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isOrgUnitOfPublication 86545861-382c-4c15-8c52-eb8e9afe6b75
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