Synthesis of chelating bidentate isocyano and cyano ligands and their metal complexes

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dc.contributor.author Angelici, Robert
dc.contributor.author Quick, Michael
dc.contributor.author Kraus, George
dc.contributor.author Kraus, George
dc.contributor.author Plummer, Daniel
dc.contributor.department Chemistry
dc.date 2018-02-17T09:25:24.000
dc.date.accessioned 2020-06-30T01:22:57Z
dc.date.available 2020-06-30T01:22:57Z
dc.date.copyright Fri Jan 01 00:00:00 UTC 1982
dc.date.issued 1982-06-01
dc.description.abstract <p>Molecular models indicate that they should chelate to metals with the donor groups at 90° with respect to each other. From reactions of the diisocyano ligand DiNC, the following complexes with chelating DiNC ligands have been isolated: Cr(CO),(DiNC), Mo(CO),(DiNC), W(CO),(DiNC), MII(CO)~(D~NC)B~, CpFe(CO)(DiNC)+, and CpFe(CS)(DiNC)+. The characterization of these complexes demonstrates that DiNC can function as a chelating ligand despite its formation of a 13-member chelate ring.</p>
dc.description.comments <p>Reprinted (adapted) with permission from <em>Inorganic Chemistry</em>, 21(6); 2178-2184. Doi: <a href="http://dx.doi.org/10.1021/ic00136a009" target="_blank">10.1021/ic00136a009</a>. Copyright 1982 American Chemical Society. </p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/chem_pubs/797/
dc.identifier.articleid 1798
dc.identifier.contextkey 7966007
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath chem_pubs/797
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/15288
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/797/0-1982_KrausGA_ACS_License_SynthesisChelatingBidentate.pdf|||Sat Jan 15 01:56:47 UTC 2022
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/797/1982_KrausGA_SynthesisChelatingBidentate.pdf|||Sat Jan 15 01:56:49 UTC 2022
dc.source.uri 10.1021/ic00136a009
dc.subject.disciplines Chemistry
dc.subject.disciplines Organic Chemistry
dc.subject.disciplines Other Chemistry
dc.subject.disciplines Polymer Chemistry
dc.title Synthesis of chelating bidentate isocyano and cyano ligands and their metal complexes
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication 773dd84a-1494-40ee-aebf-549f26a04a22
relation.isOrgUnitOfPublication 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11
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