Bond-Stretch Isomerism in Tetrasilabicyclo[1.1.0]butane Derivatives

dc.contributor.author Boatz, Jerry
dc.contributor.author Gordon, Mark
dc.contributor.author Gordon, Mark
dc.contributor.department Chemistry
dc.date 2018-02-17T07:45:22.000
dc.date.accessioned 2020-06-30T01:19:03Z
dc.date.available 2020-06-30T01:19:03Z
dc.date.copyright Mon Jan 01 00:00:00 UTC 1996
dc.date.issued 1996-04-01
dc.description.abstract <p>Bond-stretch isomerism is predicted not to occur in the parent compound Si4H6 and the substituted 1,3-di-<em>tert</em>-butyl derivative, although the existence of bond-stretch isomerism in the 1,3-dimethyl derivative is a possibility. Bulky bridgehead moieties induce a preference for a short Si−Si bridge bond, while a longer bridge bond length (2.840 Å at the MP2/6-31G(d,p) level) is predicted for the unsubstituted molecule.</p>
dc.description.comments <p>Reprinted (adapted) with permission from <em>Organometallics</em> 15 (1996): 2118, doi:<a href="http://dx.doi.org/10.1021/om9508501" target="_blank">10.1021/om9508501</a>. Copyright 1996 American Chemical Society.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/chem_pubs/292/
dc.identifier.articleid 1296
dc.identifier.contextkey 7920789
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath chem_pubs/292
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/14737
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/292/0-L_1996_Gordon_BondStretch.pdf|||Fri Jan 14 23:14:29 UTC 2022
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/292/1996_Gordon_BondStretch.pdf|||Fri Jan 14 23:14:30 UTC 2022
dc.source.uri 10.1021/om9508501
dc.subject.disciplines Chemistry
dc.title Bond-Stretch Isomerism in Tetrasilabicyclo[1.1.0]butane Derivatives
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication 1a5927c0-5a5f-440e-86e0-9da8dc6afda0
relation.isOrgUnitOfPublication 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11
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