Some studies on the V-C system

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dc.contributor.author Ghaneya, Abdel
dc.contributor.department Materials Science and Engineering
dc.date 2018-08-16T07:42:57.000
dc.date.accessioned 2020-07-02T06:10:29Z
dc.date.available 2020-07-02T06:10:29Z
dc.date.copyright Sun Jan 01 00:00:00 UTC 1984
dc.date.issued 1984
dc.description.abstract <p>The present study consists of a comprehensive critical review of the data in the literature on the V-C system together with experimental work on some areas of uncertainty in the V-C diagram. The combined results are the basis for a proposed revised V-C phase diagram;The (zeta) phase carbide was prepared by annealing a V-39.67 at. % C alloy at 1300(DEGREES)C for 220 h in a vacuum furnace. A hexagonal crystal structure with a = 2.9185 (+OR-) 0.002 (ANGSTROM) and c = 27.788 (+OR-) 0.03 (ANGSTROM) was obtained for this phase from its x-ray powder diffraction data. The peritectoid decomposition temperature was determined as 1320 (+OR-) 5(DEGREES)C by differential thermal analysis. From x-ray, metallographic, and chemical analyses, the stoichiometric composition of the (zeta) phase was determined as V(,4)C(,2.62) or (TURNEQ) V(,3)C(,2);The solvus curve for the V-rich end of the V-C system was determined by equilibrating vanadium with carbon powder at temperatures between 1100 and 1500(DEGREES)C. The maximum solubility of C in V was obtained from the results of the solubility studies as 4.5 at. % C at 1665(DEGREES)C;The composition and temperature of the VC-C eutectic alloy were experimentally determined to be 49.2 at. % C and 2645 (+OR-) 25(DEGREES)C, respectively, in agreement with published data;No evidence to support the postulated existence of an ordered V(,64)C phase was found from TEM, microscopic, or electron diffraction analyses of the matrix and precipitate phases;An attempt was made to calculate the contribution of carbon to the residual resistivity of vanadium. A value for (rho)' of 4.0 (+OR-) 1.9 x 10('-10) ohm-cm/at. ppm was obtained from the measurement of residual resistivity ratios (RRR) as a function of carbon concentration;Crystal structures data and thermodynamic properties of the reported phases of the V-C system available from the published literature are tabulated and evaluated.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/rtd/8989/
dc.identifier.articleid 9988
dc.identifier.contextkey 6347514
dc.identifier.doi https://doi.org/10.31274/rtd-180813-8945
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath rtd/8989
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/82037
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/rtd/8989/r_8423634.pdf|||Sat Jan 15 02:19:46 UTC 2022
dc.subject.disciplines Materials Science and Engineering
dc.subject.keywords Materials science and engineering
dc.subject.keywords Metallurgy
dc.title Some studies on the V-C system
dc.type article
dc.type.genre dissertation
dspace.entity.type Publication
relation.isOrgUnitOfPublication bf9f7e3e-25bd-44d3-b49c-ed98372dee5e
thesis.degree.level dissertation
thesis.degree.name Doctor of Philosophy
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