Surface Oxidation of Al-Pd-Mn and Al-Cu-Fe Alloys

dc.contributor.author Jenks, Cynthia
dc.contributor.author Pinhero, Patrick
dc.contributor.author Thiel, Patricia
dc.contributor.author Chang, S.
dc.contributor.author Anderegg, James
dc.contributor.author Besser, Matthew
dc.contributor.author Sordelet, Daniel
dc.contributor.author Thiel, Patricia
dc.contributor.department Ames Laboratory
dc.date 2018-02-13T16:15:41.000
dc.date.accessioned 2020-06-29T23:18:03Z
dc.date.available 2020-06-29T23:18:03Z
dc.date.copyright Wed Jan 01 00:00:00 UTC 1997
dc.date.embargo 2013-10-24
dc.date.issued 1997
dc.description.abstract <p>The application of ultrahigh vacuum surface analytical techniques to the study of the oxidation of Al-Pd-Mn and Al-Cu-Fe quasicrystals is presented. Comparisons of the effects of various oxidation environments are made for each material as well as for a cubic phase of Al-Pd-Mn. We find that the oxidation of the two icosahedral alloys is similar. Exposure to oxygen in vacuum, normal air, humid air and immersion in water represent progressively better oxidizing environments, resulting in increasingly deeper oxides. Oxidation of Al occurs most readily, but oxidation of other metals also becomes apparent upon going from oxygen in vacuum to immersion in water; which also attests to the effectiveness of water as an oxidant. Oxide thicknesses for both quasicrystalline alloys are comparable for each oxidation environments. Comparison of quasicrystalline to cubic Al-Pd-Mn shows that the cubic phase is more readily oxidized. In addition, while the surfaces of both quasicrystalline alloys become significantly enriched in Al upon oxidation, such enrichment is not observed for the cubic alloy. This suggests that the structure of quasicrystals plays an important role in their oxidation chemistry.</p>
dc.description.comments <p>This article is from <em>Proceedings of the Conference on New Horizons in Quasicrystals: Research and Application</em> (1997): pp. 157—164</p>
dc.identifier archive/lib.dr.iastate.edu/ameslab_conf/75/
dc.identifier.articleid 1074
dc.identifier.contextkey 4760617
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath ameslab_conf/75
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/6655
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/ameslab_conf/75/278.pdf|||Sat Jan 15 01:48:52 UTC 2022
dc.subject.disciplines Chemistry
dc.subject.disciplines Materials Science and Engineering
dc.title Surface Oxidation of Al-Pd-Mn and Al-Cu-Fe Alloys
dc.type article
dc.type.genre book_chapter
dspace.entity.type Publication
relation.isAuthorOfPublication 5e15742e-5866-486b-999c-75a0a6b554e4
relation.isOrgUnitOfPublication 25913818-6714-4be5-89a6-f70c8facdf7e
File
Original bundle
Now showing 1 - 1 of 1
Name:
278.pdf
Size:
776.57 KB
Format:
Adobe Portable Document Format
Description: