Solvent-Responsive Radical Dimers

dc.contributor.author Peterson, Joshua
dc.contributor.author Winter, Arthur
dc.contributor.author Winter, Arthur
dc.contributor.department Chemistry
dc.date 2020-07-23T19:03:25.000
dc.date.accessioned 2021-02-24T22:51:24Z
dc.date.available 2021-02-24T22:51:24Z
dc.date.copyright Wed Jan 01 00:00:00 UTC 2020
dc.date.issued 2020-07-16
dc.description.abstract <p>An air- and thermally stable aryl dicyanomethyl radical is reported that switches between two dimeric forms—a σ dimer and a π dimer—by changing the solvent. The two dimer forms exhibit unique optical properties leading to solvatochromic behavior. The solvent-responsive behavior of these radicals can be explained by the higher polarizability of the pimer than the σ dimer that leads to pimer stabilization in polar solvents.</p>
dc.description.comments <p>This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in <em>Organic Letters</em>, copyright © American Chemical Society after peer review. To access the final edited and published work see DOI: <a href="https://doi.org/10.1021/acs.orglett.0c02152" target="_blank">10.1021/acs.orglett.0c02152</a>. Posted with permission.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/chem_pubs/1247/
dc.identifier.articleid 2252
dc.identifier.contextkey 18628624
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath chem_pubs/1247
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/93624
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/1247/2020_WinterArthur_SolventResponsive.pdf|||Fri Jan 14 19:22:16 UTC 2022
dc.source.uri 10.1021/acs.orglett.0c02152
dc.subject.disciplines Organic Chemistry
dc.title Solvent-Responsive Radical Dimers
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication a2121da6-c591-494f-b9a9-595265e46ff9
relation.isOrgUnitOfPublication 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11
File
Original bundle
Now showing 1 - 1 of 1
Name:
2020_WinterArthur_SolventResponsive.pdf
Size:
877.95 KB
Format:
Adobe Portable Document Format
Description:
Collections