Solvent-Responsive Radical Dimers Peterson, Joshua Winter, Arthur Winter, Arthur
dc.contributor.department Chemistry 2020-07-23T19:03:25.000 2021-02-24T22:51:24Z 2021-02-24T22:51:24Z Wed Jan 01 00:00:00 UTC 2020 2020-07-16
dc.description.abstract <p>An air- and thermally stable aryl dicyanomethyl radical is reported that switches between two dimeric forms—a σ dimer and a π dimer—by changing the solvent. The two dimer forms exhibit unique optical properties leading to solvatochromic behavior. The solvent-responsive behavior of these radicals can be explained by the higher polarizability of the pimer than the σ dimer that leads to pimer stabilization in polar solvents.</p>
dc.description.comments <p>This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in <em>Organic Letters</em>, copyright © American Chemical Society after peer review. To access the final edited and published work see DOI: <a href="" target="_blank">10.1021/acs.orglett.0c02152</a>. Posted with permission.</p>
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dc.identifier archive/
dc.identifier.articleid 2252
dc.identifier.contextkey 18628624
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath chem_pubs/1247
dc.language.iso en
dc.source.bitstream archive/|||Fri Jan 14 19:22:16 UTC 2022
dc.source.uri 10.1021/acs.orglett.0c02152
dc.subject.disciplines Organic Chemistry
dc.title Solvent-Responsive Radical Dimers
dc.type article
dc.type.genre article
dspace.entity.type Publication
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relation.isOrgUnitOfPublication 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11
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