MOF-253-Pd(OAc)2: a recyclable MOF for transition-metal catalysis in water

dc.contributor.author Huang, Wenyu
dc.contributor.author Van Zeeland, Ryan
dc.contributor.author Li, Xinle
dc.contributor.author Huang, Wenyu
dc.contributor.author Stanley, Levi
dc.contributor.author Stanley, Levi
dc.contributor.department Ames Laboratory
dc.contributor.department Chemistry
dc.date 2018-08-06T20:30:54.000
dc.date.accessioned 2020-06-30T01:16:12Z
dc.date.available 2020-06-30T01:16:12Z
dc.date.copyright Fri Jan 01 00:00:00 UTC 2016
dc.date.issued 2016-01-01
dc.description.abstract <p>We report palladium(II)-functionalized MOF-253 (MOF-253-Pd(OAc)2) as a recyclable catalyst to form all-carbon quaternary centers via conjugate additions of arylboronic acids to β,β-disubstituted enones in aqueous media. We demonstrate MOF-253-Pd(OAc)2 can be reused 8 times to form ketone products in yields above 75% while maintaining its crystallinity. Additions of a range of stereoelectronically diverse arylboronic acids to a variety of β,β-disubstituted enones catalyzed by MOF-253-Pd(OAc)2 occur in modest-to-high yields (34–95%).</p>
dc.description.comments <p>This article is published as Van Zeeland, Ryan, Xinle Li, Wenyu Huang, and Levi M. Stanley. "MOF-253-Pd (OAc) 2: a recyclable MOF for transition-metal catalysis in water." <em>RSC Advances</em> 6, no. 61 (2016): 56330-56334. doi: <a href="http://dx.doi.org/10.1039/C6RA12746K" target="_blank">10.1039/C6RA12746K</a>. Posted with permission.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/chem_pubs/1042/
dc.identifier.articleid 2044
dc.identifier.contextkey 12601433
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath chem_pubs/1042
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/14340
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/1042/2016_Stanley_MOF253.pdf|||Fri Jan 14 18:20:47 UTC 2022
dc.source.uri 10.1039/C6RA12746K
dc.subject.disciplines Chemistry
dc.subject.disciplines Materials Chemistry
dc.subject.disciplines Organic Chemistry
dc.title MOF-253-Pd(OAc)2: a recyclable MOF for transition-metal catalysis in water
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication 6acd59cc-28ec-46dd-8bf0-51bcc56d79f9
relation.isAuthorOfPublication 06a36bbf-c631-47ba-acf0-be4aea920757
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relation.isOrgUnitOfPublication 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11
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