Use of Allylic Strain To Enforce Stereochemistry. Direct Syntheses of 7,8-Dihydroxycalamenene and Mansonone C

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2006-10-20
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Jeon, Insik
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Kraus, George
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Chemistry

The Department of Chemistry seeks to provide students with a foundation in the fundamentals and application of chemical theories and processes of the lab. Thus prepared they me pursue careers as teachers, industry supervisors, or research chemists in a variety of domains (governmental, academic, etc).

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The Department of Chemistry was founded in 1880.

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Direct syntheses of 7,8-dihydroxycalamenene and mansonone C were achieved. The cis-stereochemistry required for the synthesis of 7,8-dihydroxycalamenene was introduced by an intramolecular cyclization directed by allylic strain.

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Reprinted (adapted) with permission from Organic Letters, 8(23); 5315-5316. Doi: 10.1021/ol0621194. Copyright 2006 American Chemical Society.

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Sun Jan 01 00:00:00 UTC 2006
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