Reaction of nucleophiles with bridgehead carbocations derived from 1-bromobicyclo[2.2.2]octanes and 1-bromobicyclo[3.3.1]nonanes

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dc.contributor.author Kraus, George
dc.contributor.author Hon, Yung Son
dc.contributor.department Department of Chemistry
dc.date 2018-02-17T09:11:12.000
dc.date.accessioned 2020-06-30T01:22:21Z
dc.date.available 2020-06-30T01:22:21Z
dc.date.copyright Tue Jan 01 00:00:00 UTC 1985
dc.date.issued 1985-11-01
dc.description.abstract <p>Both intramolecular and intermolecular reactions of bridgehead carbocations are described. The carbocations are best generated from the corresponding halide with silver triflate. The carbocations reacted effectively with allyltrimethylsilane, ethyl acetoacetate, benzene, and enol silyl ethers. Bridgehead radicals were also examined.</p>
dc.description.comments <p>Reprinted (adapted) with permission from <em>The Journal of Organic Chemistry, </em>50(23); 4605-4608. Doi: <a href="http://dx.doi.org/10.1021/jo00223a035" target="_blank">10.1021/jo00223a035</a>. Copyright 1985 American Chemical Society.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/chem_pubs/717/
dc.identifier.articleid 1699
dc.identifier.contextkey 7956664
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath chem_pubs/717
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/15203
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/717/0-1985_KrausGA_ACS_License_ReactionNucleophilesBridgehead.pdf|||Sat Jan 15 01:43:24 UTC 2022
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/717/1985_KrausGA_ReactionNucleophilesBridgehead.pdf|||Sat Jan 15 01:43:25 UTC 2022
dc.source.uri 10.1021/jo00223a035
dc.subject.disciplines Chemistry
dc.subject.disciplines Environmental Chemistry
dc.subject.disciplines Inorganic Chemistry
dc.subject.disciplines Organic Chemistry
dc.subject.disciplines Other Chemistry
dc.subject.disciplines Polymer Chemistry
dc.title Reaction of nucleophiles with bridgehead carbocations derived from 1-bromobicyclo[2.2.2]octanes and 1-bromobicyclo[3.3.1]nonanes
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication 773dd84a-1494-40ee-aebf-549f26a04a22
relation.isOrgUnitOfPublication 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11
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