Reaction of nucleophiles with bridgehead carbocations derived from 1-bromobicyclo[2.2.2]octanes and 1-bromobicyclo[3.3.1]nonanes
dc.contributor.author | Kraus, George | |
dc.contributor.author | Hon, Yung Son | |
dc.contributor.department | Department of Chemistry | |
dc.date | 2018-02-17T09:11:12.000 | |
dc.date.accessioned | 2020-06-30T01:22:21Z | |
dc.date.available | 2020-06-30T01:22:21Z | |
dc.date.copyright | Tue Jan 01 00:00:00 UTC 1985 | |
dc.date.issued | 1985-11-01 | |
dc.description.abstract | <p>Both intramolecular and intermolecular reactions of bridgehead carbocations are described. The carbocations are best generated from the corresponding halide with silver triflate. The carbocations reacted effectively with allyltrimethylsilane, ethyl acetoacetate, benzene, and enol silyl ethers. Bridgehead radicals were also examined.</p> | |
dc.description.comments | <p>Reprinted (adapted) with permission from <em>The Journal of Organic Chemistry, </em>50(23); 4605-4608. Doi: <a href="http://dx.doi.org/10.1021/jo00223a035" target="_blank">10.1021/jo00223a035</a>. Copyright 1985 American Chemical Society.</p> | |
dc.format.mimetype | application/pdf | |
dc.identifier | archive/lib.dr.iastate.edu/chem_pubs/717/ | |
dc.identifier.articleid | 1699 | |
dc.identifier.contextkey | 7956664 | |
dc.identifier.s3bucket | isulib-bepress-aws-west | |
dc.identifier.submissionpath | chem_pubs/717 | |
dc.identifier.uri | https://dr.lib.iastate.edu/handle/20.500.12876/15203 | |
dc.language.iso | en | |
dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/717/0-1985_KrausGA_ACS_License_ReactionNucleophilesBridgehead.pdf|||Sat Jan 15 01:43:24 UTC 2022 | |
dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/717/1985_KrausGA_ReactionNucleophilesBridgehead.pdf|||Sat Jan 15 01:43:25 UTC 2022 | |
dc.source.uri | 10.1021/jo00223a035 | |
dc.subject.disciplines | Chemistry | |
dc.subject.disciplines | Environmental Chemistry | |
dc.subject.disciplines | Inorganic Chemistry | |
dc.subject.disciplines | Organic Chemistry | |
dc.subject.disciplines | Other Chemistry | |
dc.subject.disciplines | Polymer Chemistry | |
dc.title | Reaction of nucleophiles with bridgehead carbocations derived from 1-bromobicyclo[2.2.2]octanes and 1-bromobicyclo[3.3.1]nonanes | |
dc.type | article | |
dc.type.genre | article | |
dspace.entity.type | Publication | |
relation.isAuthorOfPublication | 773dd84a-1494-40ee-aebf-549f26a04a22 | |
relation.isOrgUnitOfPublication | 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11 |
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