Effects of anionic and nonionic surfactants on the dispersion and stability of nanoSiO2 in aqueous and cement pore solutions

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2021-06-01
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Sargam, Yogiraj
Wang, Kejin
Tsyrenova, Ayuna
Liu, Fei
Jiang, Shan
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Ames National LaboratoryCivil, Construction and Environmental EngineeringMaterials Science and EngineeringIndustrial and Manufacturing Systems Engineering
Abstract

It has been well recognized that the benefits and effectiveness of nanoparticles in cement-based materials could not be maximized if these are not well dispersed. To address this issue, in this study, different anionic (SDS and PCE) and nonionic surfactants (Tweens and Tritons) were used to disperse nanosilica (NS) in aqueous solution and cement pore solution. The results show that the dispersibility of NS in cement pore solution was improved, and the compressive strength of the cement-NS pastes increased linearly with critical micelle concentration (CMC) of nonionic surfactants. Among all surfactants studied, Triton X-405 led the paste to the highest increase in strength (33% at 1-day and 41% at 3-days) since it had the highest CMC. TEM and EDS analysis evidenced that this strength increase might be attributed to the nucleation of outer product CSH gel and its densification with calcite nanocrystals, attributed to Triton X-405 addition.

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This is a manuscript of an article published as Sargam, Yogiraj, Kejin Wang, Ayuna Tsyrenova, Fei Liu, and Shan Jiang. "Effects of anionic and nonionic surfactants on the dispersion and stability of nanoSiO2 in aqueous and cement pore solutions." Cement and Concrete Research 144 (2021): 106417. DOI: 10.1016/j.cemconres.2021.106417. Posted with permission.

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Fri Jan 01 00:00:00 UTC 2021
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