Reducing thermal transport in electrically conducting polymers: Effects of ordered mixing of polymer chains Pal, Souvik Balasubramanian, Ganesh Puri, Ishwar
dc.contributor.department Mechanical Engineering 2018-02-13T22:08:58.000 2020-06-30T06:05:50Z 2020-06-30T06:05:50Z Tue Jan 01 00:00:00 UTC 2013 2014-02-28 2013-01-01
dc.description.abstract <p>Reducing the phonon thermal conductivity of electrically conducting polymers can facilitate their use as potential thermoelectric materials. Thus, the influence of the coupling between the longitudinal and transverse phonon modes on overall thermal conductivity is explored for binary mixtures of polyaniline (PANI) and polyacetylene (PA) chains by considering various geometricpolymer mixture configurations. The molecular simulations reveal that an increase in the interfacial area available for transverse interactions between dissimilar chains enhances atomic interactions that are orthogonal to the heat transfer direction. As transverse collisions between PA and PANI chains are enhanced, the motion of longitudinal phonons is disrupted, impeding thermal transport. This enhances phonon scattering and reduces longitudinal thermal transport. While there is a nonlinear decrease in the phonon thermal conductivity with increasing interfacial contact area, there is a corresponding linear growth in the nonbonded interaction energies between the different polymers.</p>
dc.description.comments <p>The following article appeared in <em>Applied Physics Letters</em> 102 (2013): 023109. doi:<a href="" target="_blank">10.1063/1.4776676</a>. </p>
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dc.identifier archive/
dc.identifier.articleid 1065
dc.identifier.contextkey 5240029
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath me_pubs/66
dc.language.iso en
dc.source.bitstream archive/|||Sat Jan 15 01:25:11 UTC 2022
dc.source.uri 10.1063/1.4776676
dc.subject.disciplines Heat Transfer, Combustion
dc.subject.disciplines Mechanical Engineering
dc.subject.keywords Conducting polymers
dc.subject.keywords Polymers
dc.subject.keywords Phonons
dc.subject.keywords Heat transfer
dc.subject.keywords Thermal conductivity
dc.subject.keywords Atomic collisions
dc.subject.keywords Thermoelectric effects
dc.subject.keywords Atom scattering
dc.subject.keywords Carbon
dc.subject.keywords Transverse effects
dc.title Reducing thermal transport in electrically conducting polymers: Effects of ordered mixing of polymer chains
dc.type article
dc.type.genre article
dspace.entity.type Publication
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relation.isOrgUnitOfPublication 6d38ab0f-8cc2-4ad3-90b1-67a60c5a6f59
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