Metal–Organic‐Framework‐Derived Carbons: Applications as Solid‐Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis

Date
2017-03-29
Authors
Li, Xinle
Zhang, Biying
Fang, Yuhui
Sun, Weijun
Huang, Wenyu
Qi, Zhiyuan
Pei, Yuchen
Qi, Shuyan
Yuan, Pengyu
Luan, Xuechen
Goh, Tian Wei
Huang, Wenyu
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Ames Laboratory
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Mechanical Engineering
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Chemistry
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Ames LaboratoryMechanical EngineeringChemistry
Abstract

The facile pyrolysis of a bipyridyl metal‐organic framework, MOF‐253, produces N‐doped porous carbons (Cz‐MOF‐253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen‐containing MOF‐derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz‐MOF‐253‐supported Pd nanoparticles (Pd/Cz‐MOF‐253‐800) show excellent performance in a one‐pot sequential Knoevenagel condensation‐hydrogenation reaction.

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This is the peer-reviewed version of the following article: Li, Xinle, Biying Zhang, Yuhui Fang, Weijun Sun, Zhiyuan Qi, Yuchen Pei, Shuyan Qi et al. "Metal–Organic‐Framework‐Derived Carbons: Applications as Solid‐Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis." Chemistry-A European Journal 23, no. 18 (2017): 4266-4270, which has been published in final form at doi: 10.1002/chem.201605852. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. Posted with permission.

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