Transport numbers and ion mobilities in the fused salt KCl-PbCl2 Fleming, Richard Duke, F.
dc.contributor.department Ames Laboratory 2018-02-13T19:15:59.000 2020-06-29T23:18:55Z 2020-06-29T23:18:55Z 2013-12-30 1957-12-01
dc.description.abstract <p>Values of ionic transport numbers and ionic mobilities were determined for the fused system KCl-PbCl<sub>2</sub>. Cation transport numbers of 0.24 (525°C) and 0.78 (850°C) were found for PbCl<sub>2</sub> and KCl, respectively. In each mixture studied t<sub>-</sub> deviated positively and both t<sub>+</sub> and t<sub>++</sub> deviated negatively from linearity when plotted against equivalent fraction. The initial very rapid depression of total equivalent conductance from that of pure KCl, caused by addition of small amounts of PbCl<sub>2</sub>, was found to be due to the depression of the ionic conductance of K+ rather than complexing between Pb<sup>++</sup> and Cl<sup>-</sup> as had been previously supposed. Values of 0 were comp~red with those in the system LiCl-PbCl<sub>2</sub>, calculated from available literature data.</p>
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dc.identifier.contextkey 4947092
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dc.relation.ispartofseries ISC-944
dc.source.bitstream archive/|||Fri Jan 14 21:36:41 UTC 2022
dc.title Transport numbers and ion mobilities in the fused salt KCl-PbCl2
dc.type article
dc.type.genre report
dspace.entity.type Publication
relation.isOrgUnitOfPublication 25913818-6714-4be5-89a6-f70c8facdf7e
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