Transport numbers and ion mobilities in the fused salt KCl-PbCl2

dc.contributor.author Fleming, Richard
dc.contributor.author Duke, F.
dc.contributor.department Ames Laboratory
dc.date 2018-02-13T19:15:59.000
dc.date.accessioned 2020-06-29T23:18:55Z
dc.date.available 2020-06-29T23:18:55Z
dc.date.embargo 2013-12-30
dc.date.issued 1957-12-01
dc.description.abstract <p>Values of ionic transport numbers and ionic mobilities were determined for the fused system KCl-PbCl<sub>2</sub>. Cation transport numbers of 0.24 (525°C) and 0.78 (850°C) were found for PbCl<sub>2</sub> and KCl, respectively. In each mixture studied t<sub>-</sub> deviated positively and both t<sub>+</sub> and t<sub>++</sub> deviated negatively from linearity when plotted against equivalent fraction. The initial very rapid depression of total equivalent conductance from that of pure KCl, caused by addition of small amounts of PbCl<sub>2</sub>, was found to be due to the depression of the ionic conductance of K+ rather than complexing between Pb<sup>++</sup> and Cl<sup>-</sup> as had been previously supposed. Values of 0 were comp~red with those in the system LiCl-PbCl<sub>2</sub>, calculated from available literature data.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/ameslab_iscreports/181/
dc.identifier.articleid 1181
dc.identifier.contextkey 4947092
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath ameslab_iscreports/181
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/6782
dc.language.iso en
dc.relation.ispartofseries ISC-944
dc.source.bitstream archive/lib.dr.iastate.edu/ameslab_iscreports/181/17_01_00_05_AmesLab_ISC_0944_o.pdf|||Fri Jan 14 21:36:41 UTC 2022
dc.title Transport numbers and ion mobilities in the fused salt KCl-PbCl2
dc.type article
dc.type.genre report
dspace.entity.type Publication
relation.isOrgUnitOfPublication 25913818-6714-4be5-89a6-f70c8facdf7e
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