Transport numbers and ion mobilities in the fused salt KCl-PbCl2

dc.contributor.author	Fleming, Richard
dc.contributor.author	Duke, F.
dc.contributor.department	Ames Laboratory
dc.date	2018-02-13T19:15:59.000
dc.date.accessioned	2020-06-29T23:18:55Z
dc.date.available	2020-06-29T23:18:55Z
dc.date.embargo	2013-12-30
dc.date.issued	1957-12-01
dc.description.abstract	<p>Values of ionic transport numbers and ionic mobilities were determined for the fused system KCl-PbCl<sub>2</sub>. Cation transport numbers of 0.24 (525°C) and 0.78 (850°C) were found for PbCl<sub>2</sub> and KCl, respectively. In each mixture studied t<sub>-</sub> deviated positively and both t<sub>+</sub> and t<sub>++</sub> deviated negatively from linearity when plotted against equivalent fraction. The initial very rapid depression of total equivalent conductance from that of pure KCl, caused by addition of small amounts of PbCl<sub>2</sub>, was found to be due to the depression of the ionic conductance of K+ rather than complexing between Pb<sup>++</sup> and Cl<sup>-</sup> as had been previously supposed. Values of 0 were comp~red with those in the system LiCl-PbCl<sub>2</sub>, calculated from available literature data.</p>
dc.format.mimetype	application/pdf
dc.identifier	archive/lib.dr.iastate.edu/ameslab_iscreports/181/
dc.identifier.articleid	1181
dc.identifier.contextkey	4947092
dc.identifier.s3bucket	isulib-bepress-aws-west
dc.identifier.submissionpath	ameslab_iscreports/181
dc.identifier.uri	https://dr.lib.iastate.edu/handle/20.500.12876/6782
dc.language.iso	en
dc.relation.ispartofseries	ISC-944
dc.source.bitstream	archive/lib.dr.iastate.edu/ameslab_iscreports/181/17_01_00_05_AmesLab_ISC_0944_o.pdf\|\|\|Fri Jan 14 21:36:41 UTC 2022
dc.title	Transport numbers and ion mobilities in the fused salt KCl-PbCl2
dc.type	article
dc.type.genre	report
dspace.entity.type	Publication
relation.isOrgUnitOfPublication	25913818-6714-4be5-89a6-f70c8facdf7e

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