Characterizing Ionic Liquids On the Basis of Multiple Solvation Interactions Anderson, Jared Anderson, Jared Ding, Jie Welton, Thomas Armstrong, Daniel
dc.contributor.department Chemistry 2018-02-17T07:49:06.000 2020-06-30T01:19:09Z 2020-06-30T01:19:09Z Tue Jan 01 00:00:00 UTC 2002 2002-11-01
dc.description.abstract <p>Room-temperature ionic liquids (RTILs) are useful in many chemical applications. Recent publications have attempted to determine the polarity of RTILs using empirical solvent polarity scales. The results have indicated that most RTILs have similar polarities. Nevertheless, RTILs are capable of behaving quite differently when used as solvents in organic synthesis, matrixes in matrix-assisted laser desorption/ionization (MALDI) mass spectrometry, liquid−liquid extraction, and as stationary phases in gas chromatography. The work presented in this study uses a linear free energy approach to characterize 17 RTILs on the basis of their distinct multiple solvation interactions with probe solute molecules. This model provides data that can be used to help identify the interactions and properties that are important for specific chemical applications.</p>
dc.description.comments <p>Reprinted (adapted) with permission from <em>Journal of the American Chemical Society</em> 124 (2002): 14247, doi: <a href="" target="_blank">10.1021/ja028156h</a>. Copyright 2002 American Chemical Society.</p>
dc.format.mimetype application/pdf
dc.identifier archive/
dc.identifier.articleid 1329
dc.identifier.contextkey 7922876
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath chem_pubs/303
dc.language.iso en
dc.source.bitstream archive/|||Fri Jan 14 23:28:32 UTC 2022
dc.source.bitstream archive/|||Fri Jan 14 23:28:33 UTC 2022
dc.source.uri 10.1021/ja028156h
dc.subject.disciplines Analytical Chemistry
dc.subject.disciplines Chemistry
dc.subject.keywords Characterization
dc.subject.keywords desorption
dc.subject.keywords extraction
dc.subject.keywords gas chromatography
dc.subject.keywords mass spectrometry
dc.subject.keywords solvents
dc.subject.keywords energy
dc.subject.keywords matrix assisted laser desorption ionization time of flight mass spectrometry
dc.title Characterizing Ionic Liquids On the Basis of Multiple Solvation Interactions
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication 9618e7bf-b6eb-4753-affc-fca4bcc405cb
relation.isOrgUnitOfPublication 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11
Original bundle
Now showing 1 - 2 of 2
158.22 KB
Adobe Portable Document Format
93.29 KB
Adobe Portable Document Format