Stability constants of the trivalent lanthanons with some alpha-hydroxycarboxylic acids Paul, George Powell, Jack
dc.contributor.department Ames Laboratory 2018-02-13T17:05:59.000 2020-06-29T23:20:31Z 2020-06-29T23:20:31Z 2013-11-07 1965-02-01
dc.description.abstract <p>The first three stepwise formation constants of the 2-hydroxy- 3- methylbutanoate (isopropylglycolate), 2, 3-dimethyl- 2-hydroxybutanoate (methylisopropylglycolate), 3, 3-dimethyl-2-hydroxybutanoate (tertiarybutylglycolate), and 2-hydroxy-2, 3, 3-trimethylbutanoate (methyltertiarybutylglycolate) complexes of the trivalent rare earths and yttrium were determined at 25° C and an ionic strength of 0. l molar (NaCl0<sub>4</sub> ). The stabilities of the complexes followed the ionic radius trend quite regularly. The stabilities generally decreased with increasing complexity of the alkyl substituents on the ligand, but replacing a hydrogen atom by a methyl group invariably enhanced the stabilities of the complexes, especially in the case of the heavier, smaller rare-earth ions. It was postulated that the stabilities of the heavier rare-earth complexes with the methyl-substituted homologues were enhanced because of a smaller, more favorable hydroxyl-carboxyl bond angle.</p>
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dc.identifier.articleid 1098
dc.identifier.contextkey 4803784
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath ameslab_isreports/97
dc.language.iso en
dc.relation.ispartofseries IS-1122
dc.source.bitstream archive/|||Sat Jan 15 02:36:20 UTC 2022
dc.subject.disciplines Chemistry
dc.title Stability constants of the trivalent lanthanons with some alpha-hydroxycarboxylic acids
dc.type article
dc.type.genre report
dspace.entity.type Publication
relation.isOrgUnitOfPublication 25913818-6714-4be5-89a6-f70c8facdf7e
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