Size-Selective Phase-Transfer Catalysis with Interfacially Cross-Linked Reverse Micelles
| dc.contributor.author | Lee, Li-Chen | |
| dc.contributor.author | Zhao, Yan | |
| dc.contributor.author | Zhao, Yan | |
| dc.contributor.department | Chemistry | |
| dc.date | 2018-02-17T06:49:17.000 | |
| dc.date.accessioned | 2020-06-30T01:18:11Z | |
| dc.date.available | 2020-06-30T01:18:11Z | |
| dc.date.copyright | Sun Jan 01 00:00:00 UTC 2012 | |
| dc.date.issued | 2012-01-01 | |
| dc.description.abstract | <p>Cross-linking of the reverse micelles (RMs) of a triallylammonium surfactant afforded organic nanoparticles with introverted cationic groups. The cross-linked reverse micelles catalyzed size-selective biphasic reaction between sodium azide and alkyl bromides. Size selectivity of up to 9:1 was obtained for alkyl bromides with similar structures. The selectivity was influenced strongly by the size of the water pool and proposed to happen as a result of the “sieving” effect of the alkyl corona.</p> | |
| dc.description.comments | <p>Reprinted (adapted) with permission from <em>Organic Letters</em> 14 (2012): 784, doi:<a href="http://dx.doi.org/10.1021/ol203319w" target="_blank">10.1021/ol203319w</a>. Copyright 2012 American Chemical Society.</p> | |
| dc.format.mimetype | application/pdf | |
| dc.identifier | archive/lib.dr.iastate.edu/chem_pubs/179/ | |
| dc.identifier.articleid | 1171 | |
| dc.identifier.contextkey | 7886851 | |
| dc.identifier.s3bucket | isulib-bepress-aws-west | |
| dc.identifier.submissionpath | chem_pubs/179 | |
| dc.identifier.uri | https://dr.lib.iastate.edu/handle/20.500.12876/14616 | |
| dc.language.iso | en | |
| dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/179/0-L_2012_Zhao_SizeSelective.pdf|||Fri Jan 14 21:30:33 UTC 2022 | |
| dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/179/2012_Zhao_SizeSelective.pdf|||Fri Jan 14 21:30:34 UTC 2022 | |
| dc.source.uri | 10.1021/ol203319w | |
| dc.subject.disciplines | Chemistry | |
| dc.title | Size-Selective Phase-Transfer Catalysis with Interfacially Cross-Linked Reverse Micelles | |
| dc.type | article | |
| dc.type.genre | article | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | 82f430d1-77c0-43c2-8bd5-52f3787cc4ba | |
| relation.isOrgUnitOfPublication | 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11 |