Catalyzing Methanolysis of Alkyl Halides in the Interior of an Amphiphilic Molecular Basket

dc.contributor.author Ryu, Eui-Hyun
dc.contributor.author Cho, Hongkwan
dc.contributor.author Zhao, Yan
dc.contributor.author Zhao, Yan
dc.contributor.department Chemistry
dc.date 2018-02-17T06:53:30.000
dc.date.accessioned 2020-06-30T01:18:04Z
dc.date.available 2020-06-30T01:18:04Z
dc.date.copyright Mon Jan 01 00:00:00 UTC 2007
dc.date.issued 2007-11-01
dc.description.abstract <p>A molecular basket with four cholate units assembled on a cone-shaped calix[4]arene assumed reversed micelle-like conformation in 5% methanol/carbon tetrachloride. The inwardly facing hydroxyl groups on the cholates concentrated the polar solvent from the mostly nonpolar mixture. Methanolysis of alkyl halides benefited from the concentrated pocket of methanol if the substrate was capable of entering the basket. Substrates that were too large or too hydrophobic to fit within the basket showed no rate acceleration.</p>
dc.description.comments <p>Reprinted (adapted) with permission from <em>Organic Letters</em> 9 (2007): 5147, doi:<a href="http://dx.doi.org/10.1021/ol701883u" target="_blank">10.1021/ol701883u</a>. Copyright 2007 American Chemical Society.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/chem_pubs/165/
dc.identifier.articleid 1193
dc.identifier.contextkey 7887531
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath chem_pubs/165
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/14601
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/165/0-L_2007_Zhao_CatalyzingMethanolysis.pdf|||Fri Jan 14 21:01:16 UTC 2022
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/165/2007_Zhao_CatalyzingMethanolysis.pdf|||Fri Jan 14 21:01:18 UTC 2022
dc.source.uri 10.1021/ol701883u
dc.subject.disciplines Chemistry
dc.title Catalyzing Methanolysis of Alkyl Halides in the Interior of an Amphiphilic Molecular Basket
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication 82f430d1-77c0-43c2-8bd5-52f3787cc4ba
relation.isOrgUnitOfPublication 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11
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