Model for the steady-state growth of porous anodic alumina films

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2006-01-01
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Houser, Jerrod
Hebert, Kurt
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Hebert, Kurt R
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Chemical and Biological Engineering

The function of the Department of Chemical and Biological Engineering has been to prepare students for the study and application of chemistry in industry. This focus has included preparation for employment in various industries as well as the development, design, and operation of equipment and processes within industry.Through the CBE Department, Iowa State University is nationally recognized for its initiatives in bioinformatics, biomaterials, bioproducts, metabolic/tissue engineering, multiphase computational fluid dynamics, advanced polymeric materials and nanostructured materials.

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The Department of Chemical Engineering was founded in 1913 under the Department of Physics and Illuminating Engineering. From 1915 to 1931 it was jointly administered by the Divisions of Industrial Science and Engineering, and from 1931 onward it has been under the Division/College of Engineering. In 1928 it merged with Mining Engineering, and from 1973–1979 it merged with Nuclear Engineering. It became Chemical and Biological Engineering in 2005.

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1913 - present

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  • Department of Chemical Engineering (1913–1928)
  • Department of Chemical and Mining Engineering (1928–1957)
  • Department of Chemical Engineering (1957–1973, 1979–2005)
    • Department of Chemical and Biological Engineering (2005–present)

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Abstract

Simulations were developed for the distributions of electrical potential and incorporated anions in porous anodic alumina (PAA) films during steady-state growth. Predictions of a model for the potential distribution based on Laplace's equation were compared to those of the current continuity equation in conjunction with high-field conduction. It was found that Laplace's equation, which has been used previously in PAA models, resulted in strong violations of charge conservation, when the current density was evaluated using the high field conduction equation. Interface motion predicted by the current continuity equation was nearly uniform except near convex ridges on the metal-film interface. This model was extended to predict the distribution of anions in the film, since incorporated anions may provide suppression of conduction near the ridge. The spatial distribution of acid anions predicted by the model agreed with experimental observations.

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The archival version of this work was published in J. E. Houser and K. R. Hebert, "Model for the Steady-State Growth of Porous Anodic Alumina Films", ECS Trans., 3, (31) 375-385 (2007). doi: 10.1149/1.2789243

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Mon Jan 01 00:00:00 UTC 2007