A direct synthesis of c-glycosyl compounds
Is Version Of
Lactone 4 (R = Bn) can be converted into C-glycosyl compounds by reaction with an organometallic reagent followed by reduction with Et,SiH and BF3.Et20.
Reprinted (adapted) with permission from The Journal of Organic Chemistry, 53(4); 752-753. Doi: 10.1021/jo00239a009. Copyright 1988 American Chemical Society.