Ferromagnetism versus slow paramagnetic relaxation in Fe-doped Li3N

Fix, M.
Jesche, A.
Jantz, S. G.
Canfield, Paul
Bräuninger, S. A.
Klauss, H.-H.
Manna, R. S.
Pietsch, I. M.
Höppe, H. A.
Canfield, Paul
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We report on isothermal magnetization, Mossbauer spectroscopy, and magnetostriction as well as temperature-dependent alternating-current (ac) susceptibility, specific heat, and thermal expansion of single crystalline and polycrystalline Li-2(Li1-xFex)N with x = 0 and x approximate to 0.30. Magnetic hysteresis emerges at temperatures below T approximate to 50 K with coercivity fields of up to mu H-0 = 11.6 T at T = 2 K and magnetic anisotropy energies of 310 K (27 meV). The ac susceptibility is strongly frequency-dependent (f = 10-10 000 Hz) and reveals an effective energy barrier for spin reversal of Delta E approximate to 1100 K (90 meV). The relaxation times follow Arrhenius behavior for T > 25 K. ForT < 10 K, however, the relaxation times of tau approximate to 10(10) s are only weakly temperature-dependent, indicating the relevance of a quantum tunneling process instead of thermal excitations. The magnetic entropy amounts to more than 25 J mol(Fe)(-1)K(-1), which significantly exceeds R ln2, the value expected for the entropy of a ground-state doublet. Thermal expansion and magnetostriction indicate a weak magnetoelastic coupling in accordance with slow relaxation of the magnetization. The classification of Li-2(Li1-xFex)N as ferromagnet is stressed and contrasted with highly anisotropic and slowly relaxing paramagnetic behavior.


This article is published as Fix, M., Anton Jesche, Stephan G. Jantz, S. A. Bräuninger, H-H. Klauss, Rudra S. Manna, I. M. Pietsch, Henning A. Höppe, and Paul C. Canfield. "Ferromagnetism versus slow paramagnetic relaxation in Fe-doped Li 3 N." Physical Review B 97, no. 6 (2018): 064419. DOI: 10.1103/PhysRevB.97.064419. Posted with permission.