Application of Ionic Liquids in Pot-in-Pot Reactions

dc.contributor.author Çınar, Simge
dc.contributor.author Schulz, Michael
dc.contributor.author Thuo, Martin
dc.contributor.author Oyola-Reynoso, Stephanie
dc.contributor.author Bwambok, David
dc.contributor.author Gathiaka, Symon
dc.contributor.author Thuo, Martin
dc.contributor.department Materials Science and Engineering
dc.contributor.department Center for Bioplastics and Biocomposites
dc.date 2018-02-18T18:48:23.000
dc.date.accessioned 2020-06-30T06:07:34Z
dc.date.available 2020-06-30T06:07:34Z
dc.date.copyright Fri Jan 01 00:00:00 UTC 2016
dc.date.issued 2016-01-01
dc.description.abstract <p>Pot-in-pot reactions are designed such that two reaction media (solvents, catalysts and reagents) are isolated from each other by a polymeric membrane similar to matryoshka dolls (Russian nesting dolls). The first reaction is allowed to progress to completion before triggering the second reaction in which all necessary solvents, reactants, or catalysts are placed except for the starting reagent for the target reaction. With the appropriate trigger, in most cases unidirectional flux, the product of the first reaction is introduced to the second medium allowing a second transformation in the same glass reaction pot—albeit separated by a polymeric membrane. The basis of these reaction systems is the controlled selective flux of one reagent over the other components of the first reaction while maintaining steady-state catalyst concentration in the first “pot”. The use of ionic liquids as tools to control chemical potential across the polymeric membranes making the first pot is discussed based on standard diffusion models—Fickian and Payne’s models. Besides chemical potential, use of ionic liquids as delivery agent for a small amount of a solvent that slightly swells the polymeric membrane, hence increasing flux, is highlighted. This review highlights the critical role ionic liquids play in site-isolation of multiple catalyzed reactions in a standard pot-in-pot reaction.</p>
dc.description.comments <p>This article is published as Çınar, Simge, Michael D. Schulz, Stephanie Oyola-Reynoso, David K. Bwambok, Symon M. Gathiaka, and Martin Thuo. "Application of Ionic Liquids in Pot-in-Pot Reactions." <em>Molecules</em> 21, no. 3 (2016): 272, doi:<a href="http://dx.doi.org/10.3390/molecules21030272" target="_blank">10.3390/molecules21030272</a>. Posted with permission.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/mse_pubs/234/
dc.identifier.articleid 1236
dc.identifier.contextkey 10538660
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath mse_pubs/234
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/55567
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/mse_pubs/234/2016_Thuo_ApplicationIonic.pdf|||Fri Jan 14 22:48:29 UTC 2022
dc.source.uri 10.3390/molecules21030272
dc.subject.disciplines Biology and Biomimetic Materials
dc.subject.disciplines Materials Science and Engineering
dc.subject.disciplines Membrane Science
dc.subject.disciplines Polymer and Organic Materials
dc.subject.keywords pot-in-pot reactions
dc.subject.keywords unidirectional flux
dc.subject.keywords cascade reactions
dc.subject.keywords membrane separation
dc.subject.keywords multi-step synthesis
dc.title Application of Ionic Liquids in Pot-in-Pot Reactions
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication fc7bf253-7dbb-48c0-a449-cf5b94c361a7
relation.isOrgUnitOfPublication bf9f7e3e-25bd-44d3-b49c-ed98372dee5e
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