Syntheses and Structure of 8-, 7-, and 6-Membered Silacycloallenes
| dc.contributor.author | Pang, Yi | |
| dc.contributor.author | Petrich, Scott | |
| dc.contributor.author | Young, Victor | |
| dc.contributor.author | Gordon, Mark | |
| dc.contributor.author | Barton, Thomas | |
| dc.contributor.department | Ames National Laboratory | |
| dc.contributor.department | Department of Chemistry | |
| dc.contributor.department | Ames Laboratory | |
| dc.date | 2018-02-17T07:34:19.000 | |
| dc.date.accessioned | 2020-06-30T01:18:44Z | |
| dc.date.available | 2020-06-30T01:18:44Z | |
| dc.date.copyright | Fri Jan 01 00:00:00 UTC 1993 | |
| dc.date.issued | 1993-03-01 | |
| dc.description.abstract | <p>Decreasing the ring size of a cyclic allene to rings of fewer than 10 carbons results in deviation of both the normal C=C=C linearity and the orthogonality of the dihedral angle.' To date, the smallest isolable cycloallene is 1-tert-butyl-1,2-cyclooctadiene,2 and the smallest for which structural information is available is the phenylurethane derivative of cyclonona-2,3-dien-1-oJ,l which is bent to 168° and twisted to a dihedral angle of 79.8°. Encouraged by our recent success in the synthesis and structure determination of a tetrasilacyclohexyne,4 we have pursued the syntheses of strained silacycloallenes and report herein the first examples of isolable 6- and ?-membered rings containing 1,2-diene units.</p> | |
| dc.description.comments | <p>Reprinted (adapted) with permission from <em>Journal of the American Chemical Society </em>115 (1993): 2534, doi:<a href="http://dx.doi.org/10.1021/ja00059a073" target="_blank">10.1021/ja00059a073</a>. Copyright 1993 American Chemical Society.</p> | |
| dc.format.mimetype | application/pdf | |
| dc.identifier | archive/lib.dr.iastate.edu/chem_pubs/249/ | |
| dc.identifier.articleid | 1251 | |
| dc.identifier.contextkey | 7917214 | |
| dc.identifier.s3bucket | isulib-bepress-aws-west | |
| dc.identifier.submissionpath | chem_pubs/249 | |
| dc.identifier.uri | https://dr.lib.iastate.edu/handle/20.500.12876/14690 | |
| dc.language.iso | en | |
| dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/249/0-L_1993_Gordon_SynthesesStructure.pdf|||Fri Jan 14 22:55:04 UTC 2022 | |
| dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/249/1993_Gordon_SynthesesStructure.pdf|||Fri Jan 14 22:55:06 UTC 2022 | |
| dc.source.uri | 10.1021/ja00059a073 | |
| dc.subject.disciplines | Chemistry | |
| dc.title | Syntheses and Structure of 8-, 7-, and 6-Membered Silacycloallenes | |
| dc.type | article | |
| dc.type.genre | article | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | 1a5927c0-5a5f-440e-86e0-9da8dc6afda0 | |
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