23Na nuclear magnetic resonance study of yNa2S+(1 − y)[xSiS2+(1 − x)PS5/2] glassy solid electrolytes

dc.contributor.author Shastri, Ananda
dc.contributor.author Watson, Deborah
dc.contributor.author Ding, Qing-Ping
dc.contributor.author Furukawa, Yuji
dc.contributor.author Martin, Steve
dc.contributor.author Martin, Steve
dc.contributor.department Ames National Laboratory
dc.contributor.department Physics and Astronomy
dc.contributor.department Materials Science and Engineering
dc.date 2019-08-26T13:17:50.000
dc.date.accessioned 2020-06-29T23:22:31Z
dc.date.available 2020-06-29T23:22:31Z
dc.date.embargo 2020-07-08
dc.date.issued 2019-07-08
dc.description.abstract <p>23Na NMR spin lattice relaxation times, T1, and central linewidths were obtained for yNa2S + (1 − y)[xSiS2 + (1 − x)PS5/2] glassy solid electrolytes for two series of glasses, y = 0.5 and 0.67, and x = 0.1, 0.3, 0.5, 0.7, and 0.9. No pronounced mixed glass former effect in the activation energy was observed within experimental uncertainty for either series of glasses. Energy barriers to sodium motion were calculated using the Anderson-Stuart model for the y = 0.67 sample, and the results suggested that the energy barriers as a function of composition are strongly influenced by the dielectric constant of these glasses. DC Na+ ion conductivity values calculated using NMR-derived correlation times, an available Na+ ion site coordination number in the range z = 3–4, and an energy cutoff determined from the critical percolation threshold, were in agreement with the increasing trend in the experimental values for the y = 0.67 glasses. Using the same model, the conductivity values were calculated for the y = 0.50 glasses, which have as yet to be measured, and these revealed a decreasing conductivity as x increased. Sodium NMR second moment studies showed that the cation spatial arrangement followed a homogeneous distribution for y = 0.50 and 0.67 samples over most of the composition range, but deviated significantly away from this above a sodium concentration of 1.85 × 1028 m-3, suggesting a tendency for sodium to cluster under these conditions.</p>
dc.identifier archive/lib.dr.iastate.edu/ameslab_manuscripts/354/
dc.identifier.articleid 1357
dc.identifier.contextkey 14893042
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath ameslab_manuscripts/354
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/7294
dc.language.iso en
dc.relation.ispartofseries IS-J 9973
dc.source.bitstream archive/lib.dr.iastate.edu/ameslab_manuscripts/354/IS_J_9973.pdf|||Fri Jan 14 23:45:08 UTC 2022
dc.source.uri 10.1016/j.ssi.2019.115013
dc.subject.disciplines Materials Science and Engineering
dc.subject.disciplines Physics
dc.title 23Na nuclear magnetic resonance study of yNa2S+(1 − y)[xSiS2+(1 − x)PS5/2] glassy solid electrolytes
dc.type article
dc.type.genre article
dspace.entity.type Publication
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