Temperature-dependent rearrangement of 2-(2-furyl)-2-lithio-1,3-dithiane
dc.contributor.author | Taschner, Michael | |
dc.contributor.author | Kraus, George | |
dc.contributor.department | Department of Chemistry | |
dc.date | 2018-02-17T09:34:26.000 | |
dc.date.accessioned | 2020-06-30T01:22:58Z | |
dc.date.available | 2020-06-30T01:22:58Z | |
dc.date.copyright | Sun Jan 01 00:00:00 UTC 1978 | |
dc.date.issued | 1978-10-01 | |
dc.description.abstract | <p>In the course of our work directed in the area of the DielsAlder reaction, we required the preparation of compounds such as 1. It was thought the use of 2-(2-furyl)-1,3-dithian (2) as a nucleophilic acylating agent would provide an efficient entry into such a system. The use of lithiated 1,3-dithianes is well known and is the subject of two excellent reviews by Seebach.1,2 Interestingly, the synthesis and use of compound 2 had not previously been recorded in the literature. We wish to report the preparation of 2 and the temperature dependent rearrangement of the anion produced from 2.</p> | |
dc.description.comments | <p>Reprinted (adapted) with permission from <em>The Journal of Organic Chemistry,</em> 43(21); 4235-4236. Doi: <a href="http://dx.doi.org/10.1021/jo00415a054" target="_blank">10.1021/jo00415a054</a>. Copyright 1978 American Chemical Society.</p> | |
dc.format.mimetype | application/pdf | |
dc.identifier | archive/lib.dr.iastate.edu/chem_pubs/799/ | |
dc.identifier.articleid | 1838 | |
dc.identifier.contextkey | 7966991 | |
dc.identifier.s3bucket | isulib-bepress-aws-west | |
dc.identifier.submissionpath | chem_pubs/799 | |
dc.identifier.uri | https://dr.lib.iastate.edu/handle/20.500.12876/15290 | |
dc.language.iso | en | |
dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/799/0-1978_KrausGA_ACS_License_TemperatureDependent.pdf|||Sat Jan 15 01:57:05 UTC 2022 | |
dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/799/1978_KrausGA_TemperatureDependent.pdf|||Sat Jan 15 01:57:06 UTC 2022 | |
dc.source.uri | 10.1021/jo00415a054 | |
dc.subject.disciplines | Chemistry | |
dc.subject.disciplines | Organic Chemistry | |
dc.subject.disciplines | Other Chemistry | |
dc.subject.disciplines | Polymer Chemistry | |
dc.title | Temperature-dependent rearrangement of 2-(2-furyl)-2-lithio-1,3-dithiane | |
dc.type | article | |
dc.type.genre | article | |
dspace.entity.type | Publication | |
relation.isAuthorOfPublication | 773dd84a-1494-40ee-aebf-549f26a04a22 | |
relation.isOrgUnitOfPublication | 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11 |
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