Temperature-dependent rearrangement of 2-(2-furyl)-2-lithio-1,3-dithiane

dc.contributor.author Taschner, Michael
dc.contributor.author Kraus, George
dc.contributor.department Department of Chemistry
dc.date 2018-02-17T09:34:26.000
dc.date.accessioned 2020-06-30T01:22:58Z
dc.date.available 2020-06-30T01:22:58Z
dc.date.copyright Sun Jan 01 00:00:00 UTC 1978
dc.date.issued 1978-10-01
dc.description.abstract <p>In the course of our work directed in the area of the DielsAlder reaction, we required the preparation of compounds such as 1. It was thought the use of 2-(2-furyl)-1,3-dithian (2) as a nucleophilic acylating agent would provide an efficient entry into such a system. The use of lithiated 1,3-dithianes is well known and is the subject of two excellent reviews by Seebach.1,2 Interestingly, the synthesis and use of compound 2 had not previously been recorded in the literature. We wish to report the preparation of 2 and the temperature dependent rearrangement of the anion produced from 2.</p>
dc.description.comments <p>Reprinted (adapted) with permission from <em>The Journal of Organic Chemistry,</em> 43(21); 4235-4236. Doi: <a href="http://dx.doi.org/10.1021/jo00415a054" target="_blank">10.1021/jo00415a054</a>. Copyright 1978 American Chemical Society.</p>
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dc.identifier archive/lib.dr.iastate.edu/chem_pubs/799/
dc.identifier.articleid 1838
dc.identifier.contextkey 7966991
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath chem_pubs/799
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/15290
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/799/0-1978_KrausGA_ACS_License_TemperatureDependent.pdf|||Sat Jan 15 01:57:05 UTC 2022
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/799/1978_KrausGA_TemperatureDependent.pdf|||Sat Jan 15 01:57:06 UTC 2022
dc.source.uri 10.1021/jo00415a054
dc.subject.disciplines Chemistry
dc.subject.disciplines Organic Chemistry
dc.subject.disciplines Other Chemistry
dc.subject.disciplines Polymer Chemistry
dc.title Temperature-dependent rearrangement of 2-(2-furyl)-2-lithio-1,3-dithiane
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication 773dd84a-1494-40ee-aebf-549f26a04a22
relation.isOrgUnitOfPublication 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11
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