Phase diagram of unpoled lead-free (1-x)(Bi1/2Na1/2)TiO3–xBaTiO3 ceramics

dc.contributor.author Ma, C.
dc.contributor.author Tan, Xiaoli
dc.contributor.department Department of Materials Science and Engineering
dc.date 2018-02-15T16:25:30.000
dc.date.accessioned 2020-06-30T06:07:16Z
dc.date.available 2020-06-30T06:07:16Z
dc.date.copyright Fri Jan 01 00:00:00 UTC 2010
dc.date.embargo 2014-12-15
dc.date.issued 2010-09-01
dc.description.abstract <p>A phase diagram for unpoled ceramics in the lead-free <a title="View the MathML source"></a>(1−x)(Bi1/2Na1/2)TiO3–<a title="View the MathML source"></a>xBaTiO3 binary system is constructed for the first time based on transmission electron microscopy (TEM) and dielectric study. In contrast to the reported phase diagram determined using poled ceramics, an additional phase region exhibiting <em>P4bm</em> nanodomains was revealed. A new concept “relaxor antiferroelectric” was proposed to describe the unique short-range antiferroelectric order of this phase. The results suggest that electric field-induced phase transitions must be taken into consideration in optimizing the piezoelectric properties in these lead-free ceramics.</p>
dc.description.comments <p>NOTICE: this is the author’s version of a work that was accepted for publication in Solid State Communications. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Solid State Communications 150, 1497-1500 (2010). DOI: <a href="http://dx.doi.org/10.1016/j.ssc.2010.06.006" target="_blank">10.1016/j.ssc.2010.06.006</a>.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/mse_pubs/199/
dc.identifier.articleid 1193
dc.identifier.contextkey 6463290
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath mse_pubs/199
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/55529
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/mse_pubs/199/2010_Tan_PhaseDiagram.pdf|||Fri Jan 14 22:00:53 UTC 2022
dc.source.uri 10.1016/j.ssc.2010.06.006
dc.subject.disciplines Ceramic Materials
dc.subject.disciplines Metallurgy
dc.subject.keywords Lead-free piezoelectrics
dc.subject.keywords domain structure
dc.subject.keywords phase diagram
dc.subject.keywords transmission electron microscopy
dc.title Phase diagram of unpoled lead-free (1-x)(Bi1/2Na1/2)TiO3–xBaTiO3 ceramics
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication 62adb010-61c7-4fc2-a651-d8b152a926a9
relation.isOrgUnitOfPublication bf9f7e3e-25bd-44d3-b49c-ed98372dee5e
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