Aryl to Aryl Palladium Migration in the Heck and Suzuki Coupling of o-Halobiaryls
| dc.contributor.author | Campo, Marino | |
| dc.contributor.author | Zhang, Haiming | |
| dc.contributor.author | Yao, Tuanli | |
| dc.contributor.author | Ibdah, Abdellatif | |
| dc.contributor.author | McCulla, Ryan | |
| dc.contributor.author | Huang, Qinhua | |
| dc.contributor.author | Zhao, Jian | |
| dc.contributor.author | Jenks, William | |
| dc.contributor.author | Larock, Richard | |
| dc.contributor.department | Department of Chemistry | |
| dc.date | 2018-02-17T06:45:13.000 | |
| dc.date.accessioned | 2020-06-30T01:18:00Z | |
| dc.date.available | 2020-06-30T01:18:00Z | |
| dc.date.copyright | Mon Jan 01 00:00:00 UTC 2007 | |
| dc.date.issued | 2007-04-24 | |
| dc.description.abstract | <p>A novel 1,4-palladium migration between the <em>o</em>- and <em>o</em>‘-positions of biaryls has been observed in organopalladium intermediates derived from <em>o</em>-halobiaryls. The organopalladium intermediates generated by this migration have been trapped either by a Heck reaction employing ethyl acrylate or by Suzuki cross-coupling using arylboronic acids. This palladium migration can be activated or deactivated by choosing the appropriate reaction conditions. Chemical and computational evidence supports the presence of an equilibrium that correlates with the C−H acidity of the available arene positions.</p> | |
| dc.description.comments | <p>Reprinted (adapted) with permission from <em>Journal of American Chemical Society</em>, 129(19); 6298-6307. Doi: <a href="http://dx.doi.org/10.1021/ja069238z" target="_blank">10.1021/ja069238</a>z. Copyright 2007 American Chemical Society.</p> | |
| dc.format.mimetype | application/pdf | |
| dc.identifier | archive/lib.dr.iastate.edu/chem_pubs/157/ | |
| dc.identifier.articleid | 1148 | |
| dc.identifier.contextkey | 7886467 | |
| dc.identifier.s3bucket | isulib-bepress-aws-west | |
| dc.identifier.submissionpath | chem_pubs/157 | |
| dc.identifier.uri | https://dr.lib.iastate.edu/handle/20.500.12876/14592 | |
| dc.language.iso | en | |
| dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/157/0-2007_JenksWS_ACS_License_AryltoArylPalladium.pdf|||Fri Jan 14 20:45:08 UTC 2022 | |
| dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/157/2007_JenksWS_ArylToArylPalladium.pdf|||Fri Jan 14 20:45:10 UTC 2022 | |
| dc.source.uri | 10.1021/ja069238z | |
| dc.subject.disciplines | Chemistry | |
| dc.subject.disciplines | Inorganic Chemistry | |
| dc.subject.disciplines | Organic Chemistry | |
| dc.subject.disciplines | Other Chemistry | |
| dc.subject.disciplines | Polymer Chemistry | |
| dc.title | Aryl to Aryl Palladium Migration in the Heck and Suzuki Coupling of o-Halobiaryls | |
| dc.type | article | |
| dc.type.genre | article | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | 4bd6268b-7134-4d6d-9050-46681c12c965 | |
| relation.isOrgUnitOfPublication | 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11 |
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