The catalytic effect of anions on reduction reactions involving metal ions Pinkerton, Richard Duke, Frederick
dc.contributor.department Ames Laboratory 2018-02-13T16:11:53.000 2020-06-29T23:19:19Z 2020-06-29T23:19:19Z 2013-10-23 1951-06-01
dc.description.abstract <p>A model is proposed for a general activated complex AXB in oxidation-reduction reactions involving two metal ions (A) and (B). The symbol (X) would indicate the anions or other groupings which might be present, and which ordinarily would be complexed to the metals separately. The effectiveness of (X) is related to its ability to be oxidized or reduced in itself. In the case that (X) consists of oxidizable anions, the probability of electron transfer from (X) to the oxidizing metal (A) is correlated with the strength (energy) of the bond between (X) and (A). Two previous explanations of the catalytic effect of anions on such reactions are discussed, and some experiments outlined will test the validity of the proposed model.</p>
dc.format.mimetype application/pdf
dc.identifier archive/
dc.identifier.articleid 1031
dc.identifier.contextkey 4758849
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath ameslab_iscreports/38
dc.language.iso en
dc.relation.ispartofseries ISC-192
dc.source.bitstream archive/|||Fri Jan 14 23:51:43 UTC 2022
dc.subject.disciplines Chemistry
dc.subject.disciplines Inorganic Chemistry
dc.subject.keywords Ames Laboratory
dc.title The catalytic effect of anions on reduction reactions involving metal ions
dc.type article
dc.type.genre report
dspace.entity.type Publication
relation.isOrgUnitOfPublication 25913818-6714-4be5-89a6-f70c8facdf7e
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