The catalytic effect of anions on reduction reactions involving metal ions

dc.contributor.author	Pinkerton, Richard
dc.contributor.author	Duke, Frederick
dc.contributor.department	Ames Laboratory
dc.date	2018-02-13T16:11:53.000
dc.date.accessioned	2020-06-29T23:19:19Z
dc.date.available	2020-06-29T23:19:19Z
dc.date.embargo	2013-10-23
dc.date.issued	1951-06-01
dc.description.abstract	<p>A model is proposed for a general activated complex AXB in oxidation-reduction reactions involving two metal ions (A) and (B). The symbol (X) would indicate the anions or other groupings which might be present, and which ordinarily would be complexed to the metals separately. The effectiveness of (X) is related to its ability to be oxidized or reduced in itself. In the case that (X) consists of oxidizable anions, the probability of electron transfer from (X) to the oxidizing metal (A) is correlated with the strength (energy) of the bond between (X) and (A). Two previous explanations of the catalytic effect of anions on such reactions are discussed, and some experiments outlined will test the validity of the proposed model.</p>
dc.format.mimetype	application/pdf
dc.identifier	archive/lib.dr.iastate.edu/ameslab_iscreports/38/
dc.identifier.articleid	1031
dc.identifier.contextkey	4758849
dc.identifier.s3bucket	isulib-bepress-aws-west
dc.identifier.submissionpath	ameslab_iscreports/38
dc.identifier.uri	https://dr.lib.iastate.edu/handle/20.500.12876/6840
dc.language.iso	en
dc.relation.ispartofseries	ISC-192
dc.source.bitstream	archive/lib.dr.iastate.edu/ameslab_iscreports/38/17_01_00_05_AmesLab_ISC_0192_o.pdf\|\|\|Fri Jan 14 23:51:43 UTC 2022
dc.subject.disciplines	Chemistry
dc.subject.disciplines	Inorganic Chemistry
dc.subject.keywords	Ames Laboratory
dc.title	The catalytic effect of anions on reduction reactions involving metal ions
dc.type	article
dc.type.genre	report
dspace.entity.type	Publication
relation.isOrgUnitOfPublication	25913818-6714-4be5-89a6-f70c8facdf7e

File

Original bundle

Now showing 1 - 1 of 1

Name:: 17_01_00_05_AmesLab_ISC_0192_o.pdf
Size:: 2.13 MB
Format:: Adobe Portable Document Format
Description:

Download

Collections

Publications