Reactions of bridgehead halides. A synthesis of modhephene, isomodhephene, and epi-modhephene

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dc.contributor.author Kraus, George
dc.contributor.author Shi, Jianmin
dc.contributor.department Chemistry
dc.date 2018-02-17T09:00:10.000
dc.date.accessioned 2020-06-30T01:21:32Z
dc.date.available 2020-06-30T01:21:32Z
dc.date.copyright Tue Jan 01 00:00:00 UTC 1991
dc.date.issued 1991-06-01
dc.description.abstract <p>A Synthesis of modhephene has been achieved, the key feature of which is the use of a novel nucleophilic addition/rearrangement reaction to develop the carbon framework. Stereochemical control of the stereogenic center bearing the methyl group was accomplished by variation of the hydrogenation conditions. As a byproduct of this work, we have clarified structural assignments of intermediates from previous syntheses.</p>
dc.description.comments <p>Reprinted (adapted) with permission from <em>The Journal of Organic Chemistry, </em>56(13); 4147-4151. Doi: <a href="http://dx.doi.org/10.1021/jo00013a014" target="_blank">10.1021/jo00013a014</a>. Copyright 1991 American Chemical Society.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/chem_pubs/616/
dc.identifier.articleid 1638
dc.identifier.contextkey 7949917
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath chem_pubs/616
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/15092
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/616/0-1991_KrausGA_ACS_License_ReactionsBridgehead.pdf|||Sat Jan 15 01:17:12 UTC 2022
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/616/1991_KrausGA_ReactionsBridgehead.pdf|||Sat Jan 15 01:17:13 UTC 2022
dc.source.uri 10.1021/jo00013a014
dc.subject.disciplines Chemistry
dc.subject.disciplines Organic Chemistry
dc.subject.disciplines Other Chemistry
dc.subject.disciplines Polymer Chemistry
dc.title Reactions of bridgehead halides. A synthesis of modhephene, isomodhephene, and epi-modhephene
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication 773dd84a-1494-40ee-aebf-549f26a04a22
relation.isOrgUnitOfPublication 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11
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