Reactions of bridgehead halides. A synthesis of modhephene, isomodhephene, and epi-modhephene
dc.contributor.author | Kraus, George | |
dc.contributor.author | Shi, Jianmin | |
dc.contributor.department | Chemistry | |
dc.date | 2018-02-17T09:00:10.000 | |
dc.date.accessioned | 2020-06-30T01:21:32Z | |
dc.date.available | 2020-06-30T01:21:32Z | |
dc.date.copyright | Tue Jan 01 00:00:00 UTC 1991 | |
dc.date.issued | 1991-06-01 | |
dc.description.abstract | <p>A Synthesis of modhephene has been achieved, the key feature of which is the use of a novel nucleophilic addition/rearrangement reaction to develop the carbon framework. Stereochemical control of the stereogenic center bearing the methyl group was accomplished by variation of the hydrogenation conditions. As a byproduct of this work, we have clarified structural assignments of intermediates from previous syntheses.</p> | |
dc.description.comments | <p>Reprinted (adapted) with permission from <em>The Journal of Organic Chemistry, </em>56(13); 4147-4151. Doi: <a href="http://dx.doi.org/10.1021/jo00013a014" target="_blank">10.1021/jo00013a014</a>. Copyright 1991 American Chemical Society.</p> | |
dc.format.mimetype | application/pdf | |
dc.identifier | archive/lib.dr.iastate.edu/chem_pubs/616/ | |
dc.identifier.articleid | 1638 | |
dc.identifier.contextkey | 7949917 | |
dc.identifier.s3bucket | isulib-bepress-aws-west | |
dc.identifier.submissionpath | chem_pubs/616 | |
dc.identifier.uri | https://dr.lib.iastate.edu/handle/20.500.12876/15092 | |
dc.language.iso | en | |
dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/616/0-1991_KrausGA_ACS_License_ReactionsBridgehead.pdf|||Sat Jan 15 01:17:12 UTC 2022 | |
dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/616/1991_KrausGA_ReactionsBridgehead.pdf|||Sat Jan 15 01:17:13 UTC 2022 | |
dc.source.uri | 10.1021/jo00013a014 | |
dc.subject.disciplines | Chemistry | |
dc.subject.disciplines | Organic Chemistry | |
dc.subject.disciplines | Other Chemistry | |
dc.subject.disciplines | Polymer Chemistry | |
dc.title | Reactions of bridgehead halides. A synthesis of modhephene, isomodhephene, and epi-modhephene | |
dc.type | article | |
dc.type.genre | article | |
dspace.entity.type | Publication | |
relation.isAuthorOfPublication | 773dd84a-1494-40ee-aebf-549f26a04a22 | |
relation.isOrgUnitOfPublication | 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11 |
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