Copper-Catalyzed Allylic Substitution

dc.contributor.author Stanley, Levi
dc.contributor.author Hartwig, John
dc.contributor.department Department of Chemistry
dc.date 2018-02-17T10:33:21.000
dc.date.accessioned 2020-06-30T01:23:56Z
dc.date.available 2020-06-30T01:23:56Z
dc.date.copyright Fri Jan 01 00:00:00 UTC 2010
dc.date.issued 2010-01-01
dc.description.abstract <p>Allylic substitution catalyzed by copper261- 269 is a transformation that is related to allylie substitutions catalyzed by other transition metals discussed previously in this chapter, but several features of copper-catalyzed allylations make them worth differentiating. First, copper-catalyzed allylic substitutions are conducted with different types of nucleophiles than most allylic substitutions catalyzed by other metals. Second, the regioselectivity of the copper-catalyzed reactions is typically different from that of reactions catalyzed by complexes of other metals, particularly of reactions catalyzed by complexes of palladium. Thus, this last section of the chapter describes studies on allylic substitution catalyzed by copper, with an emphasis on enantioselective examples.</p>
dc.description.comments <p>This a chapter from Organotransition metal chemistry : from bonding to catalysis (2010): chapter 20.7, 999. Posted with permission.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/chem_pubs/929/
dc.identifier.articleid 1931
dc.identifier.contextkey 7997549
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath chem_pubs/929
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/15426
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/chem_pubs/929/2010_Stanley_CopperCatalyzedAllylic.pdf|||Sat Jan 15 02:30:48 UTC 2022
dc.subject.disciplines Chemistry
dc.title Copper-Catalyzed Allylic Substitution
dc.type article
dc.type.genre book_chapter
dspace.entity.type Publication
relation.isAuthorOfPublication 06a36bbf-c631-47ba-acf0-be4aea920757
relation.isOrgUnitOfPublication 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11
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