The Stability of Al11Sm3 (Al4Sm) Phases in the Al-Sm Binary System

dc.contributor.author Zhou, Shihuai
dc.contributor.author Napolitano, Ralph
dc.contributor.department Department of Materials Science and Engineering
dc.date 2018-02-14T21:28:10.000
dc.date.accessioned 2020-06-30T06:07:01Z
dc.date.available 2020-06-30T06:07:01Z
dc.date.copyright Mon Jan 01 00:00:00 UTC 2007
dc.date.embargo 2013-11-15
dc.date.issued 2007-06-06
dc.description.abstract <p>The relative stability of Al<sub>11</sub>Sm<sub>3</sub> (Al<sub>4</sub>Sm) intermetallic phases was experimentally investigated through a series of heat treatments followed by microstructural, microchemical, and X-ray diffraction (XRD) analyses. The principal findings are that the high-temperature tetragonal phase is stable from 1655 to 1333 K and that the low-temperature orthorhombic phases, <em>α</em> and <em>γ</em>, have no range of full stability but are metastable with respect to the crystalline Al and Sm reference states down to 0 K. Thermodynamic modeling is used to describe the relative energetics of stable and metastable phases along with the associated two-phase mixtures. Issues regarding transition energetics and kinetics are discussed.</p>
dc.description.comments <p>This article is from <em>Metallurgical and Materials Transactions A</em> 38 (2007): 1145, <a href="http://dx.doi.org/10.1007/s11661-007-9148-z" target="_blank">doi:10.1007/s11661-007-9148-z. </a>Posted with permission.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/mse_pubs/166/
dc.identifier.articleid 1166
dc.identifier.contextkey 6199159
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath mse_pubs/166
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/55494
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/mse_pubs/166/2007_Napolitano_StabilityPhases.pdf|||Fri Jan 14 21:02:47 UTC 2022
dc.source.uri 10.1007/s11661-007-9148-z
dc.subject.disciplines Metallurgy
dc.subject.keywords Ames Laboratory
dc.subject.keywords Materials and Engineering Physics
dc.title The Stability of Al11Sm3 (Al4Sm) Phases in the Al-Sm Binary System
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication 5d15ca50-0822-4c99-a260-7004cd21408d
relation.isOrgUnitOfPublication bf9f7e3e-25bd-44d3-b49c-ed98372dee5e
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