GC–MS and GC–NPD Determination of Formaldehyde Dimethylhydrazone in Water Using SPME

dc.contributor.author Kenessov, Bulat
dc.contributor.author Sailaukhanuly, Yerbolat
dc.contributor.author Koziel, Jacek
dc.contributor.author Koziel, Jacek
dc.contributor.author Carlsen, Lars
dc.contributor.author Nauryzbayev, Mikhail
dc.contributor.department Agricultural and Biosystems Engineering
dc.date 2018-02-17T15:20:40.000
dc.date.accessioned 2020-06-29T22:42:13Z
dc.date.available 2020-06-29T22:42:13Z
dc.date.copyright Sat Jan 01 00:00:00 UTC 2011
dc.date.issued 2011-01-01
dc.description.abstract <p>Formaldehyde dimethylhydrazone (FADMH) is one of the important transformation products of residual rocket fuel 1,1-dimethylhydrazine (1,1-DMH). Thus, recent studies show that FADMH toxicity is comparable to that of undecomposed 1,1-DMH. In this study, a new method for quantification of FADMH in water based on solid phase microextraction (SPME) in combination with gas chromatography (GC) with mass spectrometric (MS) and nitrogen-phosphorus detection (NPD) is presented. Effects of SPME fiber coating type, extraction and desorption temperatures, extraction time, and pH on analyte recovery were studied. The optimized method used 65 micron polydimethylsiloxane/divinylbenzene fiber coating for 1 min headspace extractions at 30 °C. Preferred pH and desorption temperature from the SPME fiber are >8.5 and 200 °C, respectively. Detection limits were estimated to be 1.5 and 0.5 μg L−1 for MS and NPD, respectively. The method was applied to laboratory-scale experiments to quantify FADMH. Results indicate applicability for in situ sampling and analysis and possible first-time detection of free FADMH in water.</p>
dc.description.comments <p>This article is from <em>Chromatographia</em> 73 (2011): 123–128, doi:<a href="http://dx.doi.org/10.1007/s10337-010-1820-6" target="_blank">10.1007/s10337-010-1820-6</a>. Posted with permission.</p>
dc.format.mimetype application/pdf
dc.identifier archive/lib.dr.iastate.edu/abe_eng_pubs/731/
dc.identifier.articleid 2016
dc.identifier.contextkey 8392037
dc.identifier.s3bucket isulib-bepress-aws-west
dc.identifier.submissionpath abe_eng_pubs/731
dc.identifier.uri https://dr.lib.iastate.edu/handle/20.500.12876/1528
dc.language.iso en
dc.source.bitstream archive/lib.dr.iastate.edu/abe_eng_pubs/731/2011_Kenessov_GCMSGCNPD.pdf|||Sat Jan 15 01:46:18 UTC 2022
dc.source.uri 10.1007/s10337-010-1820-6
dc.subject.disciplines Agriculture
dc.subject.disciplines Analytical Chemistry
dc.subject.disciplines Bioresource and Agricultural Engineering
dc.subject.keywords Gas chromatography—mass spectrometry; Solid phase microextraction; Environmental analysis; Rocket fuel; Formaldehyde dimethylhydrazone
dc.title GC–MS and GC–NPD Determination of Formaldehyde Dimethylhydrazone in Water Using SPME
dc.type article
dc.type.genre article
dspace.entity.type Publication
relation.isAuthorOfPublication 76fc5589-51f8-4f3c-885c-e25d8037d641
relation.isOrgUnitOfPublication 8eb24241-0d92-4baf-ae75-08f716d30801
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