Converting a Commercial Separator into a Thin-film Multi-Layer Hybrid Solid Electrolyte for Li Metal Batteries
Date
2024-01-12
Authors
Major Professor
Advisor
Committee Member
Journal Title
Journal ISSN
Volume Title
Publisher
Wiley-VCH GmbH
Abstract
To address the manifold challenges solid electrolytes (SE) do face in NMC ‖ Lithium metal batteries, we demonstrate that these can be overcome by converting a commercial Celgard 2500 separator into a jack of all trades hybrid solid electrolyte (HSE). This approach follows a multi-layer electrolyte strategy, to better cope with the very different chemistries of the cathode, the bulk electrolyte material, and the Li metal anode. A cathode-facing electrolyte layer based on lithium aluminum titanium phosphate (LATP) provides a high voltage stability of ≥4.5 V. High mechanical strength of the overall thin film electrolyte (≤50 µm) is achieved with a middle layer based on Celgard 2500. The layer on the anode side, based on polyethylene oxide (PEO), allows stable cycling of the lithium metal. High Coulombic efficiencies in NMC622 ‖ Li metal cells (99.9%) and LFP ‖ Li metal cells (99.9%) enable long term cycling with high-capacity retention of 52% and 46% after 1,000 cycles, respectively.
Series Number
Journal Issue
Is Version Of
Versions
Series
Academic or Administrative Unit
Type
article
Comments
This is an accepted manuscript of the article Published as Herbers, Lukas, William Fettkether, Silvian Stuckenberg, Debbie Bergus, Steve Martin, Martin Winter, and Peter Maria Bieker. "Converting a Commercial Separator into a Thin‐film Multi‐Layer Hybrid Solid Electrolyte for Li Metal Batteries." Batteries & Supercaps: e202300478. doi: https://doi.org/10.1002/batt.202300478. © 2024 Wiley-VCH GmbH.