A Three-Dimensional Microporous Metal–Metalloporphyrin Framework
| dc.contributor.author | Guo, Zhiyong | |
| dc.contributor.author | Yan, Dan | |
| dc.contributor.author | Wang, Hailong | |
| dc.contributor.author | Tesfagaber, Daniel | |
| dc.contributor.author | Li, Xinle | |
| dc.contributor.author | Chen, Yusheng | |
| dc.contributor.author | Huang, Wenyu | |
| dc.contributor.author | Chen, Banglin | |
| dc.contributor.department | Ames National Laboratory | |
| dc.contributor.department | Department of Chemistry | |
| dc.contributor.department | Ames Laboratory | |
| dc.date | 2018-02-17T07:26:18.000 | |
| dc.date.accessioned | 2020-06-30T01:18:40Z | |
| dc.date.available | 2020-06-30T01:18:40Z | |
| dc.date.copyright | Thu Jan 01 00:00:00 UTC 2015 | |
| dc.date.issued | 2015-01-01 | |
| dc.description.abstract | <p>A new porphyrin-based microporous MOF, {Mn(II)<sub>0.5</sub>[Mn(II)<sub>4</sub>Cl(Mn(III)Cl-ttzpp)<sub>2</sub>(H<sub>2</sub>O)<sub>4</sub>]}·(DEF)<sub>20</sub>·(CH<sub>3</sub>OH)<sub>18</sub>·(H<sub>2</sub>O)<sub>12</sub> (<strong>UTSA-57</strong>), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. <strong>UTSA-57a</strong> exhibits permanent porosity and displays moderately high performance for C<sub>2</sub>H<sub>2</sub>/CH<sub>4</sub> separation at room temperature.</p> | |
| dc.description.comments | <p>Reprinted (adapted) with permission from Inorg. Chem., 2015, 54 (1), pp 200–204. Copyright 2015 American Chemical Society</p> | |
| dc.format.mimetype | application/pdf | |
| dc.identifier | archive/lib.dr.iastate.edu/chem_pubs/239/ | |
| dc.identifier.articleid | 1237 | |
| dc.identifier.contextkey | 7908197 | |
| dc.identifier.s3bucket | isulib-bepress-aws-west | |
| dc.identifier.submissionpath | chem_pubs/239 | |
| dc.identifier.uri | https://dr.lib.iastate.edu/handle/20.500.12876/14680 | |
| dc.language.iso | en | |
| dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/239/0-2015_Huang_ThreeDimensional_License.pdf|||Fri Jan 14 22:49:58 UTC 2022 | |
| dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/239/2015_Huang_ThreeDimensional.pdf|||Fri Jan 14 22:49:59 UTC 2022 | |
| dc.source.uri | 10.1021/ic502116k | |
| dc.subject.disciplines | Materials Chemistry | |
| dc.subject.disciplines | Other Chemistry | |
| dc.subject.disciplines | Physical Chemistry | |
| dc.title | A Three-Dimensional Microporous Metal–Metalloporphyrin Framework | |
| dc.type | article | |
| dc.type.genre | article | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | 6acd59cc-28ec-46dd-8bf0-51bcc56d79f9 | |
| relation.isOrgUnitOfPublication | 25913818-6714-4be5-89a6-f70c8facdf7e | |
| relation.isOrgUnitOfPublication | 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11 |