Band Structure and Fermi Surface Nesting in LaSb2

Abstract

We use high-resolution angle resolved photoemission spectroscopy (ARPES) and density functional theory (DFT) to investigate the electronic structure of the charge density wave (CDW) system LaSb2. This compound is among an interesting group of materials that manifests both a CDW transition and lower temperature superconductivity. We find the DFT calculations to be in good agreement with our ARPES data. The Fermi surface of LaSb2 consists of two small hole pockets close to Γ and four larger pockets near the Brillouin zone (BZ) boundary. The overall features of the Fermi surface do not vary with temperature. A saddle point is present at -0.19 eV below the Fermi level at Γ. Critical points in band structure have more pronounced effects on a materials properties when they are located closer to the Fermi level, making doped LaSb2 compounds a potential interesting subject of future research. Multiple peaks are present in the generalized, electronic susceptibility calculations indicating the presence of possible nesting vectors. We were not able to detect any signatures of the CDW transition at 355 K, pointing to the subtle nature of this transition. This is unusual, given that such a high transition temperature is expected to be associated with the presence of a large CDW gap. This is confirmed through investigation of the Fermi surface and through analysis of momentum distribution curves (MDC). It is possible that changes are subtle and occur below current sensitivity of our measurements.