Li14.7Mg36.8Cu21.5Ga66: An Intermetallic Representative of a Type IV Clathrate
| dc.contributor.author | Lin, Qisheng | |
| dc.contributor.author | Corbett, John | |
| dc.contributor.department | Ames National Laboratory | |
| dc.contributor.department | Department of Chemistry | |
| dc.contributor.department | Ames Laboratory | |
| dc.date | 2018-02-18T03:43:47.000 | |
| dc.date.accessioned | 2020-06-30T01:24:16Z | |
| dc.date.available | 2020-06-30T01:24:16Z | |
| dc.date.copyright | Tue Jan 01 00:00:00 UTC 2008 | |
| dc.date.issued | 2008-01-01 | |
| dc.description.abstract | <p>Synthetic explorations in the quaternary Li−Mg−Cu−Ga system yield the novel intermetallic Li14.7(8)Mg36.8(13)Cu21.5(5)Ga66 [P6̅<em>m</em>2, <em>Z</em> = 1, <em>a</em> = 14.0803(4) Å, <em>c</em> = 13.6252 (8) Å] from within a limited composition range. This contains a unique three-dimensional anionic framework consisting of distinct interbonded Ga12 icosahedra, dimerized Li@(Cu,Mg)10Ga6 icosioctahedra, and 15-vertex Li@(Cu,Mg)9Ga6 and Li@Cu3Ga12 polyhedra. These polyhedral clusters are hosted by M20 (512), M24 (51262), and M26 (51263) (M = Li/Mg) cages, respectively. The geometries and arrangements of these cages follow those in known type IV clathrate hydrates.</p> | |
| dc.description.comments | <p>This is an article from <em>Inorganic Chemistry</em> 47 (2008): 10825, <a href="http://dx.doi.org/10.1021/ic8003245" target="_blank">doi: 10.1021/ic8003245</a>. Posted with permission.</p> | |
| dc.format.mimetype | application/pdf | |
| dc.identifier | archive/lib.dr.iastate.edu/chem_pubs/966/ | |
| dc.identifier.articleid | 1972 | |
| dc.identifier.contextkey | 9596712 | |
| dc.identifier.s3bucket | isulib-bepress-aws-west | |
| dc.identifier.submissionpath | chem_pubs/966 | |
| dc.identifier.uri | https://dr.lib.iastate.edu/handle/20.500.12876/15467 | |
| dc.language.iso | en | |
| dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/966/0-2008_Lin_IntermetallicRepresentative_License.pdf|||Sat Jan 15 02:35:58 UTC 2022 | |
| dc.source.bitstream | archive/lib.dr.iastate.edu/chem_pubs/966/2008_Lin_IntermetallicRepresentative.pdf|||Sat Jan 15 02:36:00 UTC 2022 | |
| dc.source.uri | 10.1021/ic8003245 | |
| dc.subject.disciplines | Chemistry | |
| dc.subject.disciplines | Inorganic Chemistry | |
| dc.subject.disciplines | Materials Chemistry | |
| dc.title | Li14.7Mg36.8Cu21.5Ga66: An Intermetallic Representative of a Type IV Clathrate | |
| dc.type | article | |
| dc.type.genre | article | |
| dspace.entity.type | Publication | |
| relation.isAuthorOfPublication | a3efd36c-eee8-454e-b309-21e708136671 | |
| relation.isOrgUnitOfPublication | 25913818-6714-4be5-89a6-f70c8facdf7e | |
| relation.isOrgUnitOfPublication | 42864f6e-7a3d-4be3-8b5a-0ae3c3830a11 |
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