Homoleptic organolanthanide compounds supported by the bis(dimethylsilyl)benzyl ligand
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2017-01-01
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A β-SiH functionalized benzyl anion [C(SiHMe2)2Ph]− is obtained by deprotonation of HC(SiHMe2)2Ph with KCH2Ph or by reaction of KOtBu and (Me2HSi)3CPh; LnI3(THF)n and three equivalents of this carbanion combine to provide homoleptic tris(alkyl)lanthanide compounds Ln{C(SiHMe2)2Ph}3 (Ln = La, Ce, Pr, Nd) containing secondary metal–ligand interactions.
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This article is published as Boteju, Kasuni C., Arkady Ellern, and Aaron D. Sadow. "Homoleptic organolanthanide compounds supported by the bis (dimethylsilyl) benzyl ligand." Chemical Communications 53, no. 4 (2017): 716-719. 10.1039/C6CC09304C
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Sun Jan 01 00:00:00 UTC 2017