The importance of Carbon-fiber reinforced plastics (CFRP) are widely utilized due to more high performance in engineering structures. It was well known that a nondestructive technique would be very beneficial. A new terahertz radiation has been recognized for their importance in technological applications. Recently, T-ray (terahertz ray) advances of technology and instrumentation has provided a probing field on the electromagnetic spectrum. The THz-TDS can be considered as a useful tool using general non-conducting materials; however it is quite limited to conducting materials. In order to solve various material properties, the index of refraction (n) and the absorption coefficient (α) are derived in reflective and transmission configuration using the terahertz time domain spectroscopy. However, the T-ray is limited in order to penetrate a conducting material to some degree. Here, the T-ray would not go through easily the CFRP composite laminates since carbon fibers are electrically conducting while the epoxy matrix is not. So, investigation of terahertz time domain spectroscopy (THz TDS) was made and reflection and transmission configurations were studied for a 48-ply thermoplastic PPS (poly-phenylene sulfide)-based CFRP solid laminate. It is found that the electrical conductivity of CFRP composites depends on the direction of unidirectional fibers. Also, the T-ray could penetrate a CFRP composite laminate a few ply based on the E-filed (Electrical field) of carbon fibers. The terahertz scanning images were made at the angles ranged from 0° to 180° with respect to the nominal fiber axis. So, the images were mapped out based on the electrical field (E-field) direction in the CFRP solid laminates. Also, using two-dimensional spatial Fourier transform, interface C-scan images were transformed into quantitatively angular distribution plots to show the fiber orientation information therein and to predict the orientation of the ply.