Increasing the hot-corrosion resistance of thermal barrier coating systems by the addition of oxides of Cr and Mg
dc.contributor.author | Schramm, Joseph | |
dc.contributor.department | Materials Science and Engineering | |
dc.date | 2020-08-05T05:04:18.000 | |
dc.date.accessioned | 2021-02-26T08:44:01Z | |
dc.date.available | 2021-02-26T08:44:01Z | |
dc.date.copyright | Wed Jan 01 00:00:00 UTC 2003 | |
dc.date.issued | 2003-01-01 | |
dc.description.abstract | <p>The hot corrosion of model thermal barrier coating (TBC) systems was studied at 9000C using either Na2SO4 or Na2SO4-CaSO4-MgSO4 eutectic as the corrosive salt. The yttria-stabilized zirconia (YSZ) top coat was deposited via air plasma spraying and the top coat modification methods investigated involved (1) infiltration with aqueous solutions of water-soluble compounds of chromium (e.g., chlorides, nitrates, acetates) and alkaline earth elements (e.g., MgCrO4·xH2O) followed by an oxidizing conversion treatment and (2) co-depositing Cr2O3 with the YSZ. The goal of these modifications was to deliver alkaline earth and/or chromium oxides for reaction with the molten salt, thereby inhibiting its penetration through the top-coat and/or its reactivity with the substrate alloy. It was found that these modifications could have a favorable effect on the chemistry of the salt and the hot-corrosion resistance of the TBC system. It was further found that the corrosiveness of a given salt was very dependent on the type of test conducted, i.e., thin-film pre-deposit of the salt onto the sample or submersion of the sample into molten salt.</p> | |
dc.format.mimetype | application/pdf | |
dc.identifier | archive/lib.dr.iastate.edu/rtd/20030/ | |
dc.identifier.articleid | 21029 | |
dc.identifier.contextkey | 18791800 | |
dc.identifier.doi | https://doi.org/10.31274/rtd-20200803-353 | |
dc.identifier.s3bucket | isulib-bepress-aws-west | |
dc.identifier.submissionpath | rtd/20030 | |
dc.identifier.uri | https://dr.lib.iastate.edu/handle/20.500.12876/97397 | |
dc.language.iso | en | |
dc.source.bitstream | archive/lib.dr.iastate.edu/rtd/20030/Schramm_ISU_2003_S37.pdf|||Fri Jan 14 22:19:13 UTC 2022 | |
dc.subject.keywords | Materials science and engineering | |
dc.title | Increasing the hot-corrosion resistance of thermal barrier coating systems by the addition of oxides of Cr and Mg | |
dc.type | article | |
dc.type.genre | thesis | |
dspace.entity.type | Publication | |
relation.isOrgUnitOfPublication | bf9f7e3e-25bd-44d3-b49c-ed98372dee5e | |
thesis.degree.discipline | Materials Science and Engineering | |
thesis.degree.level | thesis | |
thesis.degree.name | Master of Science |
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