Macroscale Control of Reactivity using 3D Printed Materials with Intrinsic Catalytic Properties

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Date
2020-09-05
Authors
Manzano, J. Sebastián
Wang, Hsin
Qi, Long
Slowing, Igor
Slowing, Igor
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Ames Laboratory
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Chemistry
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Ames LaboratoryChemistry
Abstract

The morphology of heterogeneous catalysts can impact their performance. However, standard manufacturing methods like extrusion or pelleting offer little options for tailoring catalyst shape. Herein, stereolithographic 3D printing is used to produce catalysts with controlled topologies to enhance their performance. A series of magnetic stir-bar compartments (SBC) were 3D printed and tested as catalysts for sucrose hydrolysis. The SBC were printed using acrylic acid (AA) and 1,6-hexanediol diacrylate (HDDA) as acid sites and hydrophobic crosslinking domains, respectively. Variations in the number and tilt direction of the SBC blades produced significant changes in their apparent catalytic activities. These changes resulted from differences in the fraction of active surface effectively interacting with the reactants in solution, as revealed by computational fluid dynamics simulations. Moreover, varying HDDA:AA ratios in SBC regulated reactant-surface interactions to control catalytic activity. Overall, 3D printing catalysts enables quick performance optimization by simultaneously controlling macroscopic structure and molecular composition.

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This is a manuscript of an article published as Manzano, J. Sebastián, Hsin Wang, Long Qi, and Igor I. Slowing. "Macroscale Control of Reactivity using 3D Printed Materials with Intrinsic Catalytic Properties." Applied Catalysis A: General 605 (2020): 117794. DOI: 10.1016/j.apcata.2020.117794. Posted with permission.

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