Reaction of nucleophiles with bridgehead carbocations derived from 1-bromobicyclo[2.2.2]octanes and 1-bromobicyclo[3.3.1]nonanes
Date
1985-11-01
Authors
Hon, Yung Son
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Abstract
Both intramolecular and intermolecular reactions of bridgehead carbocations are described. The carbocations are best generated from the corresponding halide with silver triflate. The carbocations reacted effectively with allyltrimethylsilane, ethyl acetoacetate, benzene, and enol silyl ethers. Bridgehead radicals were also examined.
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Reprinted (adapted) with permission from The Journal of Organic Chemistry, 50(23); 4605-4608. Doi: 10.1021/jo00223a035. Copyright 1985 American Chemical Society.
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Tue Jan 01 00:00:00 UTC 1985