Synthesis of chelating bidentate isocyano and cyano ligands and their metal complexes

Supplemental Files
Date
1982-06-01
Authors
Angelici, Robert
Quick, Michael
Kraus, George
Kraus, George
Plummer, Daniel
Major Professor
Advisor
Committee Member
Journal Title
Journal ISSN
Volume Title
Publisher
Altmetrics
Authors
Research Projects
Organizational Units
Chemistry
Organizational Unit
Journal Issue
Series
Department
Chemistry
Abstract

Molecular models indicate that they should chelate to metals with the donor groups at 90° with respect to each other. From reactions of the diisocyano ligand DiNC, the following complexes with chelating DiNC ligands have been isolated: Cr(CO),(DiNC), Mo(CO),(DiNC), W(CO),(DiNC), MII(CO)~(D~NC)B~, CpFe(CO)(DiNC)+, and CpFe(CS)(DiNC)+. The characterization of these complexes demonstrates that DiNC can function as a chelating ligand despite its formation of a 13-member chelate ring.

Comments

Reprinted (adapted) with permission from Inorganic Chemistry, 21(6); 2178-2184. Doi: 10.1021/ic00136a009. Copyright 1982 American Chemical Society.

Description
Keywords
Citation
DOI
Collections